$\dot Q = \sum\limitsj^{\mathcal C} \dot n{j, 1} \cdot \Delta H^\circ_j(T)
\sum\limitsj^{\mathcal C} \dot n{j, 0} \cdot \Delta H^\circ_j(T_0) = \sum\limitsj^{\mathcal C}\dot n{j, 0}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_0))$
Reaktor: Berücksichtigte (unabhängige) Reaktionen:
$ 2.0 CO+ 2.0 H_2\rightleftharpoons 1.0 CO_2+1.0 CH_4 \quad K(T)=7.39082e-05\\ 1.0 CO+ 3.0 H_2\rightleftharpoons 1.0 H_2O+1.0 CH_4 \quad K(T)=0.000123279\\ 1.5 H_2+ 0.5 N_2\rightleftharpoons 1.0 NH_3 \quad K(T)=0.000143712\\ 2.0 CO+ 4.0 H_2\rightleftharpoons 2.0 CH_4+1.0 O_2 \quad K(T)=3.46185e-23 $
Isothermer Reaktor. Lösung nach A.1.1. $\Rightarrow \{n_{j,1}\}_j^{\mathcal C}, \{\xi_{i,1}\}_i^{\mathcal R}$
Totale zu tauschende Energie:
$\dot Q = \sum\limitsj^{\mathcal C}\dot n{j, 0}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_0))
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 1}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_1))$
$ 1.0 H_2+ 1.0 CO_2\rightleftharpoons 1.0 CO+1.0 H_2O \quad K(T)=0.00533179 $
Isothermer Reaktor. Lösung nach A.1.1. $\Rightarrow \{n_{j,2}\}_j^{\mathcal C}, \{\xi_{i,2}\}_i^{\mathcal R}$
Totale zu tauschende Energie:
$\dot Q = \sum\limitsj^{\mathcal C}\dot n{j, 1}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_1))
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 2}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_2))$
Anteil der Verflüssigung an der Vorkühlerleistung
$\dot Q_V = \sum\limits_j^{\mathcal C}[(1-\Psi) \cdot n_{j,2} \cdot x_{j,2}] \cdot \Delta_V H_j^{\circ}(T)$
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 4}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_4))$
$ 0.75 CO2+ 0.25 CH4\rightleftharpoons1.0 CO+0.5 H2O \quad K(T)=0.00409148\\ 0.5 CO2+ 1.0 H2O\rightleftharpoons0.5 CH4+1.0 O2 \quad K(T)=2.82336e-34\\ 0.5 H2O+ 0.25 CH4\rightleftharpoons1.0 H2+0.25 CO2 \quad K(T)=0.0848723\\ $
Isothermer Reaktor. Lösung nach A.1.1. $\Rightarrow \{\dot n_{j,5}\}_j^{\mathcal C}, \{\xi_{i,5}\}_i^{\mathcal R}$
Totale zu tauschende Energie:
$\dot Q = \sum\limitsj^{\mathcal C}\dot n{j, 4}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_4))
Adiabate Verdichtung. Lösung nach A.3.1. $\Rightarrow T_{2,rev}, \dot W_{1-2,rev}, T_2, \dot W_{1-2}$
Abkühler: von $T_{2,Verdichter}$ zurück auf Betriebstemperatur $T_5$=350°C:
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 5}\cdot(\Delta H^\circ_j(T_5)-\Delta H^\circ_j(T_{2,Verdichter}))$
Komponentenbilanz:
$\dot n_{j,6} = \dot n_{j,5}+{\mathcal R}\cdot \dot n_{j, 8}$
Energiebilanz (Objektivfunktion):
$0=\sum\limitsj^{\mathcal C} \dot n{j, 5} \cdot \Delta H^\circ_j(T_5)
Lösung $\Rightarrow T_6$
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 6}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_6))$
$ 2.0 H_2O+ 1.0 CH_4+ 1.333 N_2\rightleftharpoons 1.0 CO2+2.667 NH_3 \quad K(T)=1.93108e-09\\ 1.0 H_2O+ 1.0 CH4+ 1.0 N_2\rightleftharpoons1.0 CO+2.0 NH_3 \quad K(T)=2.91601e-10\\ 2.0 H_2O+ 0.667 N_2\rightleftharpoons 1.333 NH_3+1.0 O2 \quad K(T)=1.47386e-41\\ 0.667 NH_3\rightleftharpoons 1.0 H_2+0.333 N_2 \quad K(T)=6.03022 $
Adiabater Reaktor. Lösung nach A.1.2. $\Rightarrow \{n_{j,7}\}_j^{\mathcal C}, \{\xi_{i,7}\}_i^{\mathcal R}, T_7$
$\dot Q = \sum\limits_j^{\mathcal C}\dot n_{j, 2}\cdot(\Delta H^\circ_j(T)-\Delta H^\circ_j(T_7))$
Anteil der Verflüssigung an der Vorkühlerleistung
$\dot Q_V = \sum\limits_j^{\mathcal C}[(1-\Psi) \cdot n_{j,7}\cdot x_{j,8}] \cdot \Delta_V H_j^{\circ}(T)$
Rücklaufstrom in den Mischer (Schritt 7) hinein schicken, und wieder 7-9 berechnen, bis keine Änderung bei der Komponentenbilanz mehr ist:
$\dot n_{j,6} = \dot n_{j,5}+{\mathcal R}\cdot \dot n_{j, 8}$
$\begin{array}{llll} \dot n_j &= \dot n_{j, 0} + \sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}& \quad &\mathcal{C}\\ K_{i}(T)\cdot p^{-\sum\limits_{j}^{\mathcal C}{\nu_{ij}}} &= \prod\limits_{j}^{\mathcal C}{\left(\frac{\dot n_j}{\sum\limits_j^{\mathcal{C}}\dot n_j}\right)^{\nu_{ij}}} &\quad& \mathcal{R} \\ &&& \overline{\mathcal{C}+\mathcal{R}}\\ \end{array}$
$\begin{array}{lll} 0 &= \dot Q & + \sum\limits_i(\dot n_i \Delta H_i^{\circ}(T))_{ein}- \sum\limits_i\dot n_i (\Delta H_i^{\circ}(T))_{aus}\\ &= 0 &+ \sum\limits_i\dot n_{i,0} \cdot\Delta H_i^{\circ}(T_{ein}) - \sum\limits_i\dot n_{i}\cdot\Delta H_i^{\circ}(T) \\ \end{array}\\ $
Gleichungen: $\mathcal{C} + \mathcal{R} + 1$
Variablen: $\mathcal{C}$ ($\dot n_j$), $\mathcal{R}$ ($\xi_j$), $T_2$
$\Rightarrow$ Durch Einsetzen der Stoffbilanzen in den Gleichgewichtsbedingungen:
Gleichungen: $\mathcal{R} + 1$
Variablen: $\mathcal{R}$ ($\xi_j$), $T_2$
Stark nichtlineares System. Lösung nach dem Liniensuchverfahren [2]
$\begin{array}{llll} 0 &= -K_{i}(T)\cdot p^{-\sum\limits_{j}^{\mathcal C}{\nu_{ij}}} + \prod\limits_{j}^{\mathcal C}{\left(\frac{\dot n_{j, 0} + \sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}}{\sum\limits_j^{\mathcal{C}}\dot n_{j, 0} + \sum\limits_{j}^{\mathcal{C}}\sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}}\right)^{\nu_{ij}}}\\ \end{array}$
$\begin{array}{ll} {{\partial f_j}\over{\partial \xi_i}}=&\prod\limits_{k}^{\mathcal C}{\left(\frac{\dot n_{k, 0} + \sum\limits_{j}^{\mathcal R}{\nu_{jk} \cdot \xi_j}}{\sum\limits_k^{\mathcal{C}}\dot n_{k, 0} + \sum\limits_{k}^{\mathcal{C}}\sum\limits_{j}^{\mathcal R}{\nu_{jk} \cdot \xi_j}}\right)^{\nu_{ij}}} \cdot \left[\sum\limits_k^{\mathcal{C}}\frac{\nu_{i k} \nu_{j k}}{\dot n_{k, 0} + \sum\limits_{j}^{\mathcal R}{\nu_{jk} \cdot \xi_j}} -\frac{\left(\sum\limits_k^{\mathcal C}\nu_{ik}\right)\cdot\left(\sum\limits_k^{\mathcal C}\nu_{jk}\right)}{\sum\limits_k^{\mathcal{C}}\dot n_{k, 0} + \sum\limits_{k}^{\mathcal{C}}\sum\limits_{j}^{\mathcal R}{\nu_{jk} \cdot \xi_j}}\right]\\ \end{array}$
Division durch Null vermeiden. $\mathcal S: \text{Substrate} (\nu_{ij}<0), \mathcal P: \text{Produkte} (\nu_{ij}>0), \mathcal C: \text{Komponente} \\ \mathcal C=\mathcal S+\mathcal P$.
$\begin{array}{ll} 0 &= \left[K_{i}(T)\cdot p^{-\sum\limits_{j}^{\mathcal C}{\nu_{ij}}}\right]\cdot n_T^{\sum\limits_{j}^{\mathcal C}{\nu_{ij}}}\cdot\prod\limits_{j}^{\mathcal S}n_j^{-\nu_{ij}} - \prod\limits_{j}^{\mathcal P}n_j^{\nu_{ij}}\\ n_j &= \dot n_{j, 0} + \sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}\\ n_T & =\sum\limits_j^{\mathcal{C}}\dot n_{j, 0} + \sum\limits_{j}^{\mathcal{C}}\sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}\\ \end{array}$
$\begin{array}{ll} {{\partial f_j}\over{\partial \xi_i}}=&-\left[K_{j}(T)\cdot p^{-\sum\limits_{k}^{\mathcal C}{\nu_{jk}}}\right]\cdot n_T^{\sum\limits_{k}^{\mathcal C}{\nu_{jk}}}\cdot\prod\limits_{k}^{\mathcal S}n_k^{-\nu_{jk}}\cdot\left[\left(\sum\limits_k^{\mathcal{S}}\frac{\nu_{i k} \nu_{j k}}{n_k}\right)- \frac{\left(\sum\limits_k{\nu_{jk}}\right)\cdot\left(\sum\limits_k{\nu_{ik}}\right)}{n_T}\right] \\ &-\prod\limits_{k}^{\mathcal P}n_k^{+\nu_{jk}}\cdot \left(\sum\limits_k^{\mathcal{P}}\frac{\nu_{i k} \nu_{j k}}{n_k}\right)\\ \end{array}$
$\begin{array}{llll} f_i &= 0 =& \left[K_{i}(T)\cdot p^{-\sum\limits_{j}^{\mathcal C}{\nu_{ij}}}\right]\cdot n_T^{\sum\limits_{j}^{\mathcal C}{\nu_{ij}}}\cdot\prod\limits_{j}^{\mathcal S}n_j^{-\nu_{ij}} - \prod\limits_{j}^{\mathcal P}n_j^{\nu_{ij}}\\ n_j &=& \dot n_{j, 0} + \sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}\\ n_T &=&\sum\limits_j^{\mathcal{C}}\dot n_{j, 0} + \sum\limits_{j}^{\mathcal{C}}\sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}\\ f_q &= 0 =& + \sum\limits_i^{\mathcal{C}}\dot n_{i,0} \cdot\Delta H_i^{\circ}(T_{ein}) -\sum\limits_j^{\mathcal{C}} (\dot n_{j, 0} + \sum\limits_{i}^{\mathcal R}{\nu_{ij} \cdot \xi_i}) \cdot\Delta H_j^{\circ}(T)\\ \end{array}$
$\begin{array}{ll} {{\partial f_j}\over{\partial \xii}}=&-\left[K{j}(T)\cdot p^{-\sum\limits{k}^{\mathcal C}{\nu{jk}}}\right]\cdot nT^{\sum\limits{k}^{\mathcal C}{\nu{jk}}}\cdot\prod\limits{k}^{\mathcal S}nk^{-\nu{jk}}\cdot\left[\left(\sum\limitsk^{\mathcal{S}}\frac{\nu{i k} \nu_{j k}}{n_k}\right)- \frac{\left(\sum\limitsk{\nu{jk}}\right)\cdot\left(\sum\limitsk{\nu{ik}}\right)}{nT}\right] \ &-\prod\limits{k}^{\mathcal P}nk^{+\nu{jk}}\cdot \left(\sum\limitsk^{\mathcal{P}}\frac{\nu{i k} \nu_{j k}}{n_k}\right)\ {{\partial fj}\over{\partial T}}=&+\left[K{j}(T)\cdot p^{-\sum\limits{k}^{\mathcal C}{\nu{jk}}}\right]\cdot nT^{\sum\limits{k}^{\mathcal C}{\nu{jk}}}\cdot\prod\limits{k}^{\mathcal S}nk^{-\nu{jk}} \cdot \left(\frac{\partial ln K_j(T)}{\partial T}\right)\ \frac{d ln K_j(T)}{d T}=& \frac{\Delta Hr^\circ_i(T)}{R T^2} \hspace{2cm} \text{(...Theor.)}\ {{\partial f_q}\over{\partial \xi_i}}=& -\sum\limitsk^{\mathcal{C}} (\nu{ik}) \cdot\Delta H_k^{\circ}(T)\ {{\partial f_q}\over{\partial T}}=&
Rachford - Rice [2]
Variablen: (N) Molbrüche in der Flüssigkeit $\{\dot x_i\}$, (N) Molbrüche im Gas $\{y_i\}$, (1) Dampf/Flüssigkeit Verhältnis
Gleichungen: (N) Stoffbilanzen, (N) Isotherme Gleichgewichtsbedingungen, (1) Zwangsbedingung
$\dot F z_i = \dot V y_i + \dot L x_i $
$(\hat{\phi_i}^V P) y_i^V=(\hat{\phi_i}^L P) x_i^L \hspace{2cm} K_i\equiv{{y_i}\over{x_i}}={{\hat{\phi_i}^L}\over{\hat{\phi_i}^V}}$
$0 = \sum\limits_i y_i - \sum\limits_i x_i$
System zu einer Funktion einer Veränderlichen reduziert: $\psi\equiv(V/F)$
$\begin{array}{ll} z_i &= \psi y_i + (1-\psi) x_i \\ &= \psi x_i K_i + (1-\psi) x_i \\ x_i &={{z_i}\over{1+\psi(K_i-1)}} \hspace{3cm} y_i &={{z_i K_i}\over{1+\psi(K_i-1)}}\\ \Rightarrow 0 &= \sum\limits_i y_i - \sum\limits_i x_i = \sum\limits_i {{z_i(K_i-1)}\over{1+\psi(K_i-1)}}\\ \end{array}$
(Ojektivfunktion)
Lösung nach Rachford Rice-Algorithmus [5]
Idealgas:
$dS = \frac{dQ_{rev}}{T}=\frac{Cp^{IG}}{T}dT-\frac{R}{P}dP=0$
$dW = dU = C_v dT$ .... (Adiabat, dU=0+dW, jedoch wird eigentlich folgende Gleichung benutzt: $W=\Delta H=\int\limits_{T_1}^{T_2}Cp^{IG}dT$. Vergleich [7] SVN: Gl. 7.22 S. 276 (288 pdf) mit Gl.3.34 S. 78 (90 pdf)).
Temperatur der reversiblen Verdichtung: $T_{2,rev}$
$\int\limits_{T_1}^{T_2, rev}\frac{Cp^{IG}}{T}dT=R\cdot ln \frac{P_2}{P_1}$
Temperaturabhängigkeiten der Wärmekapazität werden in den „Cp-Mittelwerten" eingeschlossen, damit rein formal direkt gelöst werden kann:
$\left<Cp^{IG}\right>_S\equiv \frac{1}{T_{2,rev}/T_1} \int\limits_{T_1}^{T_2, rev}\frac{Cp^{IG}}{T}dT$
$\left<Cp^{IG}\right>_H\equiv \frac{1}{T_{2,rev}-T_1} \int\limits_{T_1}^{T_2, rev}Cp^{IG}dT$
Es gilt dann:
$\frac{T_{2,rev}}{T_1}=\left(\frac{P_2}{P_1}\right)^{R/\left<Cp^{IG}\right>_S}$
Als Funktion von ($\kappa$ nach [6], $\gamma$ nach [7]), $\kappa\equiv Cp^{IG} / Cv^{IG}$
$\frac{R}{Cp^{IG}}=\frac{Cp^{IG}-Cv^{IG}}{Cp^{IG}}=\frac{\kappa-1}{\kappa} \Leftrightarrow \kappa=\frac{1}{1-R/Cp^{IG}}$
$\begin{array}{lr} (1) & \quad T_{2,rev}=T_1\cdot\left(\frac{P_2}{P_1}\right)^{\frac{\kappa-1}{\kappa}}\\ \end{array}$
$W=\left<Cp^{IG}\right>_H\cdot (T_{2,rev}-T_1)=\frac{\gamma\cdot R\cdot T_1}{\gamma-1}\cdot\left[\left(\frac{P_2}{P_1}\right)^{\frac{\gamma-1}{\gamma}}-1\right]$
Reversible Verdichterleistung:
- Methode 1. [6]
$\begin{array}{lr} (2) & \quad \begin{array}{ll} \dot W_{1-2, rev} &=\sum\limits_j^{\mathcal C}\dot n_{j, 2}\cdot\Delta H_j^{\circ}(T_{2, rev})-\sum\limits_j^{\mathcal C}\dot n_{j, 1}\cdot\Delta H_j^{\circ}(T_1)\\ &=\sum\limits_j^{\mathcal C}\dot n_{j, 1}\cdot(\Delta H_j^{\circ}(T_{2,rev})-\Delta H_j^{\circ}(T_{1}))\\ \end{array} \end{array}$
$\quad\text{(hier }h(T, P)\rightsquigarrow \Delta H_j^{\circ}(T)\text{)}$, d.h. Druck bei Enthalpieberechnung vernachlässigt, denn das Idealgas wird vorausgesetzt, wonach $H^R=0$
- Methode 2. [7]
$\begin{array}{lr} (2) & \quad \dot W_{1-2, rev}=\dot n_1 \cdot \frac{R\cdot T_1 \cdot \gamma}{\gamma-1}\cdot \left[\left(\frac{P_2}{P_1}\right)^{\frac{\gamma-1}{\gamma}}-1 \right] \end{array}$
$\eta_{therm}=0,72$
$\eta_{mech}=1,0$
Tatsächliche Arbeit:
$\begin{array}{lr} (3) & \quad \dot W_{1-2} = \frac{\dot W_{1-2, rev}}{\eta_{therm}\cdot \eta_{mech}} \end{array}$
Die tatsächliche Temperatur am Auslaß wird iterativ berechnet, denn sowohl $\Delta H_j^{\circ}(T_2)$ als auch $\left<Cp^{IG}\right>_H$ sind temperaturabhängig.
- Methode 1: [6] Ojektivfunktion:
$\begin{array}{lr} (4) & \quad 0 = \sum\limits_j^{\mathcal C}\dot n_{j, 1}\cdot(\Delta H_j^{\circ}(T_{2})-\Delta H_j^{\circ}(T_{1}))-\frac{\dot W_{1-2, rev}}{\eta_{therm}\cdot \eta_{mech}} \end{array}$
- Methode 2: [7] Ojektivfunktion:
$\begin{array}{lr} (4) & \quad 0 = \left<Cp^{IG}\right>_H\cdot (T_{2}-T_1)-\frac{\dot W_{1-2, rev}}{\eta_{therm}\cdot \eta_{mech}} \end{array}$
Zusammenfassung:
[1] MYERS, Andrea K.; MYERS, Alan L. Numerical solution of chemical equilibria with simultaneous reactions. The Journal of chemical physics, 1986, 84. Jg., Nr. 10, S. 5787-5795.
[2] Jr., J. E. Dennis ; Schnabel, Robert B.: Numerical Methods for Unconstrained Optimization and Nonlinear Equations. Philadelphia: SIAM, 1996.
[3] Barin, Ihsan: Thermochemical Data of Pure Substances. Weinheim, New York: VCH, 1993.
[4] e.V., VDI: VDI-Wärmeatlas. Wiesbaden: Springer Berlin Heidelberg, 2013.
[5] Henley, Ernest J. ; Seader, J. D. ; Roper, D. Keith: Separation Process Principles. New York: Wiley, 2011.
[6] Gmehling, Jürgen ; Kolbe, Bärbel ; Kleiber, Michael ; Rarey, Jürgen: Chemical Thermodynamics for Process Simulation. New York: John Wiley & Sons, 2012.
[7] Smith, Joseph Mauk ; Ness, Hendrick C. Van ; Abbott, Michael M.: Introduction to chemical engineering thermodynamics. New York: McGraw-Hill, 2005.
In [1]:
import warnings
warnings.filterwarnings('ignore')
import bsp_pat_ue_03_2
========================================
Dampf-Reformierung: Vorwärmer + Reaktor
========================================
Vormärmer (auf T= 1268.15 °K), Q: 801968,17827302974183 kW
Berücksichtigte (unabhängige) Reaktionen:
2.0 CO+ 2.0 H2<<==>>1.0 CO2+1.0 CH4 K(T)=7.39082e-05
1.0000000000000002 CO+ 3.0 H2<<==>>1.0 H2O+1.0000000000000002 CH4 K(T)=0.000123279
1.5 H2+ 0.5 N2<<==>>1.0 NH3 K(T)=0.000143712
2.0 CO+ 4.0 H2<<==>>2.0 CH4+1.0 O2 K(T)=3.46185e-23
Isothermisch betriebener Reaktor, Q: 735341,15632314386312 kW
Totale zu tauschende Energie, Q: 1537309,3345961733721 kW
n_{CO}=13625,70494775651423 kmol/h
n_{H2}=57728,619700805276807 kmol/h
n_{CO2}=5809,5057644187072583 kmol/h
n_{H2O}=41055,276079679781105 kmol/h
n_{CH4}=564,78928782477976256 kmol/h
n_{NH3}=57,683762576922099186 kmol/h
n_{AR}=150 kmol/h
n_{O2}=0,0037218631478026509285 kmol/h
n_{N2}=11671,158118711538918 kmol/h
n_T=130662,74138363669044 kmol/h
y_{CO}=0,10428148685286121877
y_{H2}=0,44181393325668288918
y_{CO2}=0,044461838951943576104
y_{H2O}=0,31420798036938529796
y_{CH4}=0,004322496848328870149
y_{NH3}=0,0004414706286282312972
y_{AR}=0,0011479936698985024855
y_{O2}=2,8484502226039715266e-08
y_{N2}=0,089322770937769066513
T: 1268.15 °K
p: 35 bar
H: -72402776.528519 J/kmol
Gesamtfehler: 2.30692595962236e-08
========================================
========================================
Wassergashift: Vorkühler + Reaktor
========================================
Vorkühler (auf T= 483.15 °K), Q: -985366,13835413742345 kW
Berücksichtigte Reaktionen:
1.0 H2+ 1.0 CO2<<==>>1.0 CO+1.0 H2O K(T)=0.00533179
Isothermisch betriebener Reaktor, Q: -148279,44339609821327 kW
Totale zu tauschende Energie, Q: -1133645,581750235986 kW
n_{CO}=262,43623308968358288 kmol/h
n_{H2}=71091,888415472101769 kmol/h
n_{CO2}=19172,774479085539497 kmol/h
n_{H2O}=27692,007365012952505 kmol/h
n_{CH4}=564,78928782477976256 kmol/h
n_{NH3}=57,683762576922099186 kmol/h
n_{AR}=150 kmol/h
n_{O2}=0,0037218631478026509285 kmol/h
n_{N2}=11671,158118711538918 kmol/h
n_T=130662,74138363669044 kmol/h
y_{CO}=0,0020085008955930978153
y_{H2}=0,54408691921395102575
y_{CO2}=0,14673482490921169186
y_{H2O}=0,21193499441211716139
y_{CH4}=0,004322496848328870149
y_{NH3}=0,0004414706286282312972
y_{AR}=0,0011479936698985024855
y_{O2}=2,8484502226039715266e-08
y_{N2}=0,089322770937769066513
T: 483.15 °K
p: 35 bar
H: -103636807.370703 J/kmol
Gesamtfehler: [[6.70198588e-09]]
========================================
========================================
Trocknung: Vorkühler + Abscheider
========================================
Vorkühler (auf T= 293.15 °K), Q: -502447,49886184721254 kW
Dampfphase:
n_{CO}=262,4360199768953521 kmol/h
n_{H2}=71091,71959557615628 kmol/h
n_{CO2}=19160,517151931053377 kmol/h
n_{H2O}=75,316800224054787805 kmol/h
n_{CH4}=564,78556888775688094 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0,0037217897537182276745 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=103028,99587262334535 kmol/h
y_{CO}=0,0025472054517747875872
y_{H2}=0,69001662098761695763
y_{CO2}=0,18597208474857959692
y_{H2O}=0,00073102527678111793759
y_{CH4}=0,0054818118346760267082
y_{NH3}=0,00051510512583656769669
y_{AR}=0,0014558754153826650342
y_{O2}=3,612371179788978006e-08
y_{N2}=0,11328023503843330511
H2/N2 Verhältnis: 6.09123578136566
Stoechiometrisches Verhältnis: 3
T: 293.15 °K
p: 35 bar
H: -74225864.611222 J/kmol
========================================
Flüssigphase (Abwasser):
n_{CO}=0,00021311278821939787513 kmol/h
n_{H2}=0,16881989595010482574 kmol/h
n_{CO2}=12,25732715447689003 kmol/h
n_{H2O}=27616,690564788892516 kmol/h
n_{CH4}=0,0037189370229437244617 kmol/h
n_{NH3}=4,6129986932874551542 kmol/h
n_{AR}=0,0026178379045153571739 kmol/h
n_{O2}=7,3394084423167842412e-08 kmol/h
n_{N2}=0,0092505195843291965901 kmol/h
n_T=27633,745511013305077 kmol/h
x_{CO}=7,7120485940729072454e-09
x_{H2}=6,1091934092345341172e-06
x_{CO2}=0,00044356372716337525786
x_{H2O}=0,99938282175663828433
x_{CH4}=1,3457954953746073194e-07
x_{NH3}=0,0001669335302882097151
x_{AR}=9,4733372406747012738e-08
x_{O2}=2,6559586138315086848e-12
x_{N2}=3,3475446101022086774e-07
T: 293.15 °K
p: 35 bar
H: -242027292.604286 J/kmol
========================================
========================================
CO2-Abschneider:
========================================
Abtrennung-Faktor (CO2): 0.05 - Produkt
n_{CO}=262,4360199768953521 kmol/h
n_{H2}=71091,71959557615628 kmol/h
n_{CO2}=958,02585759655278252 kmol/h
n_{H2O}=75,316800224054787805 kmol/h
n_{CH4}=564,78556888775688094 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0,0037217897537182276745 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=84826,504578288833727 kmol/h
y_{CO}=0,0030937974077982380132
y_{H2}=0,83808380351171429812
y_{CO2}=0,011293944768316641417
y_{H2O}=0,000887892299682615572
y_{CH4}=0,0066581261563890088359
y_{NH3}=0,00062563893381524526578
y_{AR}=0,0017682843694644821871
y_{O2}=4,3875316709334403173e-08
y_{N2}=0,13758846867750293419
T: 293.15 °K
p: 35 bar
H: -5673653.276627 J/kmol
========================================
Abtrennung-Faktor (CO2): 0.95 - Abfluss
n_{CO}=0 kmol/h
n_{H2}=0 kmol/h
n_{CO2}=18202,491294334500708 kmol/h
n_{H2O}=0 kmol/h
n_{CH4}=0 kmol/h
n_{NH3}=0 kmol/h
n_{AR}=0 kmol/h
n_{O2}=0 kmol/h
n_{N2}=0 kmol/h
n_T=18202,491294334500708 kmol/h
y_{CO}=0
y_{H2}=0
y_{CO2}=1
y_{H2O}=0
y_{CH4}=0
y_{NH3}=0
y_{AR}=0
y_{O2}=0
y_{N2}=0
T: 293.15 °K
p: 35 bar
H: -393690072.811983 J/kmol
========================================
========================================
Methanisierung: Aufheizer + Reaktor
========================================
Aufheizer (auf T= 623.15 °K), Q: 229031,84859929344384 kW
Berücksichtigte (unabhängige) Reaktionen:
0.75 CO2+ 0.25 CH4<<==>>1.0 CO+0.5 H2O K(T)=0.00409148
0.5 CO2+ 1.0 H2O<<==>>0.5 CH4+1.0 O2 K(T)=2.82336e-34
0.5 H2O+ 0.25 CH4<<==>>1.0 H2+0.25 CO2 K(T)=0.0848723
Isothermisch betriebener Reaktor, Q: -63789,184448484782479 kW
Totale zu tauschende Energie, Q: 165242,66415080873412 kW
n_{CO}=1,8986244685947894457e-07 kmol/h
n_{H2}=66472,300662783483858 kmol/h
n_{CO2}=1,3353687245398760922e-07 kmol/h
n_{H2O}=2253,8119785166272777 kmol/h
n_{CH4}=1785,2474461378058095 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=82385,577101999006118 kmol/h
y_{CO}=2,3045592874152741876e-12
y_{H2}=0,80684390400623418049
y_{CO2}=1,6208768227557572574e-12
y_{H2O}=0,0273568755332775429
y_{CH4}=0,021669417256464037352
y_{NH3}=0,00064417542184512955206
y_{AR}=0,0018206752618408976029
y_{O2}=0
y_{N2}=0,1416649525164127843
T: 623.15 °K
p: 35 bar
H: 1378850.756326 J/kmol
Gesamtfehler: 2.7021508537823955e-09
========================================
========================================
Verdichtung: Adiabater Verdichter + Abkühler
========================================
Verdichten (auf p= 180.0 bar), W: 338973880,47486966848 W
gamma=Cp/Cv=: 1.36884
T: 1098.23 °K
n_{CO}=1,8986244685947894457e-07 kmol/h
n_{H2}=66472,300662783483858 kmol/h
n_{CO2}=1,3353687245398760922e-07 kmol/h
n_{H2O}=2253,8119785166272777 kmol/h
n_{CH4}=1785,2474461378058095 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=82385,577101999006118 kmol/h
y_{CO}=2,3045592874152741876e-12
y_{H2}=0,80684390400623418049
y_{CO2}=1,6208768227557572574e-12
y_{H2O}=0,0273568755332775429
y_{CH4}=0,021669417256464037352
y_{NH3}=0,00064417542184512955206
y_{AR}=0,0018206752618408976029
y_{O2}=0
y_{N2}=0,1416649525164127843
T: 1098.23 °K
p: 180 bar
H: 16222273.157505 J/kmol
========================================
Abkühlen (zurück auf T= 623.15 °K), Q: -339689,97796940658009 kW
n_{CO}=1,8986244685947894457e-07 kmol/h
n_{H2}=66472,300662783483858 kmol/h
n_{CO2}=1,3353687245398760922e-07 kmol/h
n_{H2O}=2253,8119785166272777 kmol/h
n_{CH4}=1785,2474461378058095 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=82385,577101999006118 kmol/h
y_{CO}=2,3045592874152741876e-12
y_{H2}=0,80684390400623418049
y_{CO2}=1,6208768227557572574e-12
y_{H2O}=0,0273568755332775429
y_{CH4}=0,021669417256464037352
y_{NH3}=0,00064417542184512955206
y_{AR}=0,0018206752618408976029
y_{O2}=0
y_{N2}=0,1416649525164127843
T: 623.15 °K
p: 180 bar
H: 1378850.756326 J/kmol
========================================
========================================
==============1. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0
Temperatur der Mischung: 573.15 °K
Vorwärmer (auf T= 573.15 °K), Q: -34311,300301955074247 kW
n_{CO}=1,8986244685947894457e-07 kmol/h
n_{H2}=66472,300662783483858 kmol/h
n_{CO2}=1,3353687245398760922e-07 kmol/h
n_{H2O}=2253,8119785166272777 kmol/h
n_{CH4}=1785,2474461378058095 kmol/h
n_{NH3}=53,07076388363465469 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=0 kmol/h
n_{N2}=11671,148868191954534 kmol/h
n_T=82385,577101999006118 kmol/h
y_{CO}=2,3045592874152741876e-12
y_{H2}=0,80684390400623418049
y_{CO2}=1,6208768227557572574e-12
y_{H2O}=0,0273568755332775429
y_{CH4}=0,021669417256464037352
y_{NH3}=0,00064417542184512955206
y_{AR}=0,0018206752618408976029
y_{O2}=0
y_{N2}=0,1416649525164127843
T: 573.15 °K
p: 180 bar
H: -120449.065706 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,6783343421088323604e-08 kW (adiabat)
n_{CO}=4,9311163842284875506e-05 kmol/h
n_{H2}=52252,767884164211864 kmol/h
n_{CO2}=1,0461943279528275523e-05 kmol/h
n_{H2O}=2253,8119087385130115 kmol/h
n_{CH4}=1785,2473866880977766 kmol/h
n_{NH3}=9532,7594087481684255 kmol/h
n_{AR}=149,99738216209547659 kmol/h
n_{O2}=-3,2428589527428488686e-25 kmol/h
n_{N2}=6931,3045457596872438 kmol/h
n_T=72905,888576033888967 kmol/h
y_{CO}=6,7636736627738974931e-10
y_{H2}=0,71671532855222741532
y_{CO2}=1,4349929043958452098e-10
y_{H2O}=0,030913989977476265952
y_{CH4}=0,024487012250406288427
y_{NH3}=0,13075431347094013113
y_{AR}=0,0020574110691437843233
y_{O2}=-4,448006897770481439e-30
y_{N2}=0,095071943859939347932
T: 775.61 °K
p: 180 bar
H: -136110.621286 J/kmol
Gesamtfehler: 30048.000289537442
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -357380,27685884822858 kW
Dampfphase (zum Splitter):
n_{CO}=4,9284479085610095742e-05 kmol/h
n_{H2}=52228,872303327967529 kmol/h
n_{CO2}=9,9646139881232100315e-06 kmol/h
n_{H2O}=19,215588359022060416 kmol/h
n_{CH4}=1780,5473221543518321 kmol/h
n_{NH3}=5243,6659823905183657 kmol/h
n_{AR}=149,63162467389122412 kmol/h
n_{O2}=-3,2345033444283020014e-25 kmol/h
n_{N2}=6927,8116071542744976 kmol/h
n_T=66349,744487309115357 kmol/h
y_{CO}=7,4279832519021539602e-10
y_{H2}=0,78717518361298910445
y_{CO2}=1,5018315540451831676e-10
y_{H2O}=0,00028961058563351351272
y_{CH4}=0,026835782651182363973
y_{NH3}=0,079030688400109863623
y_{AR}=0,0022551951905627294279
y_{O2}=-4,874929616056327291e-30
y_{N2}=0,10441353859272159421
H2/N2 Verhältnis: 7.539014520745886
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -5828576.498723 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=2,6684756674789672953e-08 kmol/h
n_{H2}=23,895580836239915357 kmol/h
n_{CO2}=4,9732929140506644442e-07 kmol/h
n_{H2O}=2234,5963203794917717 kmol/h
n_{CH4}=4,700064533746269646 kmol/h
n_{NH3}=4289,0934263576509693 kmol/h
n_{AR}=0,36575748820425107999 kmol/h
n_{O2}=-8,3556083145471092821e-28 kmol/h
n_{N2}=3,4929386054126601024 kmol/h
n_T=6556,1440887247599676 kmol/h
x_{CO}=4,0701906995328833203e-12
x_{H2}=0,0036447613918655485249
x_{CO2}=7,5856980116088516111e-11
x_{H2O}=0,34084002605921082107
x_{CH4}=0,00071689463709937329555
x_{NH3}=0,65420975675904824431
x_{AR}=5,5788506708771968656e-05
x_{O2}=-1,274469902996682822e-31
x_{N2}=0,00053277331320848654757
T: 294.15 °K
p: 180 bar
H: -112671547.675879 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,942758326848808066e-05 kmol/h
n_{H2}=41783,097842662376934 kmol/h
n_{CO2}=7,9716911904985693804e-06 kmol/h
n_{H2O}=15,372470687217649754 kmol/h
n_{CH4}=1424,4378577234815566 kmol/h
n_{NH3}=4194,9327859124150564 kmol/h
n_{AR}=119,70529973911298782 kmol/h
n_{O2}=-2,5876026755426421522e-25 kmol/h
n_{N2}=5542,2492857234201438 kmol/h
n_T=53079,795589847301017 kmol/h
y_{CO}=7,4279832524504837164e-10
y_{H2}=0,7871751836710978445
y_{CO2}=1,5018315541560476002e-10
y_{H2O}=0,00028961058565489235326
y_{CH4}=0,026835782653163362671
y_{NH3}=0,079030688405943849695
y_{AR}=0,002255195190729206503
y_{O2}=-4,874929616416191947e-30
y_{N2}=0,10441353860042933144
T: 294.15 °K
p: 180 bar
H: -5828576.498723 J/kmol
========================================
Abgas:
n_{CO}=9,8568958171220167767e-06 kmol/h
n_{H2}=10445,774460665590595 kmol/h
n_{CO2}=1,9929227976246414981e-06 kmol/h
n_{H2O}=3,8431176718044115503 kmol/h
n_{CH4}=356,10946443087027546 kmol/h
n_{NH3}=1048,7331964781035367 kmol/h
n_{AR}=29,92632493477823985 kmol/h
n_{O2}=-6,4690066888566019366e-26 kmol/h
n_{N2}=1385,5623214308545812 kmol/h
n_T=13269,948897461821616 kmol/h
y_{CO}=7,4279832524504826824e-10
y_{H2}=0,78717518367109773347
y_{CO2}=1,5018315541560473417e-10
y_{H2O}=0,00028961058565489235326
y_{CH4}=0,026835782653163362671
y_{NH3}=0,079030688405943863573
y_{AR}=0,002255195190729206503
y_{O2}=-4,8749296164161912464e-30
y_{N2}=0,10441353860042931756
T: 294.15 °K
p: 180 bar
H: -5828576.498723 J/kmol
========================================
========================================
==============1. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 493.383 °K
Vorwärmer (auf T= 573.15 °K), Q: 90632,993452262599021 kW
n_{CO}=3,9617445715347561616e-05 kmol/h
n_{H2}=108255,39850544586079 kmol/h
n_{CO2}=8,1052280629525574396e-06 kmol/h
n_{H2O}=2269,1844492038444514 kmol/h
n_{CH4}=3209,6853038612875935 kmol/h
n_{NH3}=4248,0035497960498105 kmol/h
n_{AR}=269,7026819012084502 kmol/h
n_{O2}=0 kmol/h
n_{N2}=17213,398153915375588 kmol/h
n_T=135465,37269184630713 kmol/h
y_{CO}=2,924544105117435659e-10
y_{H2}=0,79913705144194224772
y_{CO2}=5,9832471589548967492e-11
y_{H2O}=0,016751029463195264008
y_{CH4}=0,023693769411926468571
y_{NH3}=0,031358593457379811686
y_{AR}=0,0019909344841557573454
y_{O2}=0
y_{N2}=0,1270686213891135119
T: 573.15 °K
p: 180 bar
H: 963320.293597 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -1,2842396895090740547e-07 kW (adiabat)
n_{CO}=2,1150315856807494816e-05 kmol/h
n_{H2}=86838,289606724589248 kmol/h
n_{CO2}=3,1784033967673741207e-06 kmol/h
n_{H2O}=2269,1844775246236168 kmol/h
n_{CH4}=3209,6853272552421004 kmol/h
n_{NH3}=18526,076098871104477 kmol/h
n_{AR}=269,7026819012084502 kmol/h
n_{O2}=-4,4191342478973300471e-19 kmol/h
n_{N2}=10074,361879377849618 kmol/h
n_T=121187,30009598335891 kmol/h
y_{CO}=1,745258442102094919e-10
y_{H2}=0,71656262279914240132
y_{CO2}=2,6227198677171612858e-11
y_{H2O}=0,018724606255996902038
y_{CH4}=0,026485327461813996247
y_{NH3}=0,15287143194210936481
y_{AR}=0,0022255028512690460014
y_{O2}=-3,6465324703143528155e-24
y_{N2}=0,083130508488915122456
T: 755.148 °K
p: 180 bar
H: 1076816.980739 J/kmol
Gesamtfehler: 32.003339510910074
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -573232,1886202635942 kW
Dampfphase (zum Splitter):
n_{CO}=2,11172823546106815e-05 kmol/h
n_{H2}=86741,255650312537909 kmol/h
n_{CO2}=2,9070683801424558513e-06 kmol/h
n_{H2O}=27,978542910683611211 kmol/h
n_{CH4}=3188,0934575651326668 kmol/h
n_{NH3}=9045,9538800427599199 kmol/h
n_{AR}=268,24503585462360888 kmol/h
n_{O2}=-4,3941743367455694422e-19 kmol/h
n_{N2}=10059,771749884566816 kmol/h
n_T=109331,29834059464338 kmol/h
y_{CO}=1,9314947023109755568e-10
y_{H2}=0,79337991009908737094
y_{CO2}=2,6589534965776237569e-11
y_{H2O}=0,00025590607021725353312
y_{CH4}=0,029159934125779506803
y_{NH3}=0,082738923045356627117
y_{AR}=0,0024535063602125857171
y_{O2}=-4,0191367004200782554e-24
y_{N2}=0,092011820058452167825
H2/N2 Verhältnis: 8.622586854548453
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6164944.684297 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=3,3033502196814130419e-08 kmol/h
n_{H2}=97,033956412033319339 kmol/h
n_{CO2}=2,7133501662491789884e-07 kmol/h
n_{H2O}=2241,2059346139403715 kmol/h
n_{CH4}=21,591869690109440683 kmol/h
n_{NH3}=9480,1222188283427386 kmol/h
n_{AR}=1,457646046584895716 kmol/h
n_{O2}=-2,4959911151761037466e-21 kmol/h
n_{N2}=14,590129493283745532 kmol/h
n_T=11856,001755388662787 kmol/h
x_{CO}=2,7862261565746170308e-12
x_{H2}=0,0081843743306515923802
x_{CO2}=2,2885878585040438843e-11
x_{H2O}=0,18903556032559770683
x_{CH4}=0,0018211763240088914197
x_{NH3}=0,79960533207318129634
x_{AR}=0,00012294583595238983958
x_{O2}=-2,1052553526559514924e-25
x_{N2}=0,0012306112800209996049
T: 294.15 °K
p: 180 bar
H: -82724435.690720 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=1,689382588368854791e-05 kmol/h
n_{H2}=69393,004520250033238 kmol/h
n_{CO2}=2,3256547041139645116e-06 kmol/h
n_{H2O}=22,382834328546891811 kmol/h
n_{CH4}=2550,4747660521065882 kmol/h
n_{NH3}=7236,7631040342075721 kmol/h
n_{AR}=214,59602868369887574 kmol/h
n_{O2}=-3,5153394693964557463e-19 kmol/h
n_{N2}=8047,8173999076534528 kmol/h
n_T=87465,038672475726344 kmol/h
y_{CO}=1,9314947023518377621e-10
y_{H2}=0,79337991011587172263
y_{CO2}=2,6589534966338752698e-11
y_{H2O}=0,00025590607022266738824
y_{CH4}=0,029159934126396405696
y_{NH3}=0,082738923047107004738
y_{AR}=0,0024535063602644912456
y_{O2}=-4,0191367005051061699e-24
y_{N2}=0,092011820060398735732
T: 294.15 °K
p: 180 bar
H: -6164944.684297 J/kmol
========================================
Abgas:
n_{CO}=4,2234564709221361306e-06 kmol/h
n_{H2}=17348,251130062504672 kmol/h
n_{CO2}=5,8141367602849102203e-07 kmol/h
n_{H2O}=5,5957085821367211764 kmol/h
n_{CH4}=637,61869151302641967 kmol/h
n_{NH3}=1809,1907760085514383 kmol/h
n_{AR}=53,649007170924704724 kmol/h
n_{O2}=-8,7883486734911369585e-20 kmol/h
n_{N2}=2011,9543499769129085 kmol/h
n_T=21866,25966811892431 kmol/h
y_{CO}=1,9314947023518380205e-10
y_{H2}=0,79337991011587183365
y_{CO2}=2,6589534966338755929e-11
y_{H2O}=0,00025590607022266738824
y_{CH4}=0,029159934126396405696
y_{NH3}=0,082738923047107018616
y_{AR}=0,0024535063602644912456
y_{O2}=-4,0191367005051061699e-24
y_{N2}=0,09201182006039874961
T: 294.15 °K
p: 180 bar
H: -6164944.684297 J/kmol
========================================
========================================
==============2. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 452.805 °K
Vorwärmer (auf T= 573.15 °K), Q: 172022,3876221824612 kW
n_{CO}=1,7083688330548025479e-05 kmol/h
n_{H2}=135865,3051830335171 kmol/h
n_{CO2}=2,4591915765679521473e-06 kmol/h
n_{H2O}=2276,1948128451740558 kmol/h
n_{CH4}=4335,7222121899121703 kmol/h
n_{NH3}=7289,8338679178423263 kmol/h
n_{AR}=364,59341084579438075 kmol/h
n_{O2}=-3,5153394693964557463e-19 kmol/h
n_{N2}=19718,966268099604349 kmol/h
n_T=169850,61577447471791 kmol/h
y_{CO}=1,0058066762166767386e-10
y_{H2}=0,79991058356499333826
y_{CO2}=1,4478555555154611035e-11
y_{H2O}=0,013401157260845460162
y_{CH4}=0,025526679384823801333
y_{NH3}=0,042919090017296039619
y_{AR}=0,002146553365045767315
y_{O2}=-2,0696654253312067846e-24
y_{N2}=0,11609593629193652731
T: 573.15 °K
p: 180 bar
H: 1140183.593852 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -9,9623998006184900849e-08 kW (adiabat)
n_{CO}=1,4596762642403195685e-05 kmol/h
n_{H2}=110131,96166707950761 kmol/h
n_{CO2}=1,8634573573710102045e-06 kmol/h
n_{H2O}=2276,194816523568079 kmol/h
n_{CH4}=4335,7222152725717024 kmol/h
n_{NH3}=24445,396205324708717 kmol/h
n_{AR}=364,59341084579438075 kmol/h
n_{O2}=-2,5895183035691419758e-18 kmol/h
n_{N2}=11141,185099396172518 kmol/h
n_T=152695,05343090253882 kmol/h
y_{CO}=9,5594207634293229889e-11
y_{H2}=0,72125428553529635778
y_{CO2}=1,2203783393770910208e-11
y_{H2O}=0,014906801270766706705
y_{CH4}=0,028394647487612098558
y_{NH3}=0,16009291497046904129
y_{AR}=0,0023877224746561937982
y_{O2}=-1,6958756982530209638e-23
y_{N2}=0,072963628153401668963
T: 746.185 °K
p: 180 bar
H: 1268285.259804 J/kmol
Gesamtfehler: 72564624.0506876
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -710375,69717367331032 kW
Dampfphase (zum Splitter):
n_{CO}=1,4566747799516768105e-05 kmol/h
n_{H2}=109976,06348856045224 kmol/h
n_{CO2}=1,6808641325580972884e-06 kmol/h
n_{H2O}=31,60401029358932945 kmol/h
n_{CH4}=4298,7067746588663795 kmol/h
n_{NH3}=11634,96973692753636 kmol/h
n_{AR}=362,17380333479661658 kmol/h
n_{O2}=-2,5716104901264467842e-18 kmol/h
n_{N2}=11119,956219679806964 kmol/h
n_T=137423,47404970266507 kmol/h
y_{CO}=1,059989779775381823e-10
y_{H2}=0,80027130916394229043
y_{CO2}=1,2231273762848431249e-11
y_{H2O}=0,00022997534090781721365
y_{CH4}=0,031280731362293180686
y_{NH3}=0,084665082274220329617
y_{AR}=0,0026354580673800015629
y_{O2}=-1,8713036530965553738e-23
y_{N2}=0,080917443664407395776
H2/N2 Verhältnis: 9.889972704562245
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6406047.494243 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=3,0014842886429419445e-08 kmol/h
n_{H2}=155,89817851907213253 kmol/h
n_{CO2}=1,8259322481291310143e-07 kmol/h
n_{H2O}=2244,590806229977261 kmol/h
n_{CH4}=37,015440613705386852 kmol/h
n_{NH3}=12810,426468397168719 kmol/h
n_{AR}=2,4196075109977024375 kmol/h
n_{O2}=-1,7907813442695290946e-20 kmol/h
n_{N2}=21,228879716363966423 kmol/h
n_T=15271,579381199891941 kmol/h
x_{CO}=1,9654052891023917341e-12
x_{H2}=0,010208386090248268777
x_{CO2}=1,1956407406810613036e-11
x_{H2O}=0,14697830200635769726
x_{CH4}=0,0024238122130409217245
x_{NH3}=0,83884097051291350855
x_{AR}=0,00015843859045541969569
x_{O2}=-1,1726235379511322319e-24
x_{N2}=0,0013900906506202157648
T: 294.15 °K
p: 180 bar
H: -74401760.839235 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=1,1653398239613415501e-05 kmol/h
n_{H2}=87980,850790848373435 kmol/h
n_{CO2}=1,3446913060464780001e-06 kmol/h
n_{H2O}=25,283208234871466402 kmol/h
n_{CH4}=3438,9654197270929217 kmol/h
n_{NH3}=9307,9757895420298155 kmol/h
n_{AR}=289,7390426678372819 kmol/h
n_{O2}=-2,0572883921011577355e-18 kmol/h
n_{N2}=8895,9649757438455708 kmol/h
n_T=109938,77923976213788 kmol/h
y_{CO}=1,0599897797845173867e-10
y_{H2}=0,80027130917083966199
y_{CO2}=1,2231273762953848309e-11
y_{H2O}=0,00022997534090979929785
y_{CH4}=0,031280731362562777531
y_{NH3}=0,084665082274950037577
y_{AR}=0,0026354580674027151647
y_{O2}=-1,871303653112683744e-23
y_{N2}=0,080917443665104796247
T: 294.15 °K
p: 180 bar
H: -6406047.494243 J/kmol
========================================
Abgas:
n_{CO}=2,9133495599033534516e-06 kmol/h
n_{H2}=21995,212697712086083 kmol/h
n_{CO2}=3,3617282651161939414e-07 kmol/h
n_{H2O}=6,3208020587178648242 kmol/h
n_{CH4}=859,74135493177300305 kmol/h
n_{NH3}=2326,9939473855065444 kmol/h
n_{AR}=72,434760666959306263 kmol/h
n_{O2}=-5,1432209802528924127e-19 kmol/h
n_{N2}=2223,991243935960938 kmol/h
n_T=27484,694809940527193 kmol/h
y_{CO}=1,0599897797845175159e-10
y_{H2}=0,80027130917083955097
y_{CO2}=1,2231273762953848309e-11
y_{H2O}=0,00022997534090979929785
y_{CH4}=0,031280731362562777531
y_{NH3}=0,0846650822749500237
y_{AR}=0,0026354580674027155984
y_{O2}=-1,8713036531126834502e-23
y_{N2}=0,080917443665104796247
T: 294.15 °K
p: 180 bar
H: -6406047.494243 J/kmol
========================================
========================================
==============3. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 434.152 °K
Vorwärmer (auf T= 573.15 °K), Q: 225422,02561355952639 kW
n_{CO}=1,1843260686472893069e-05 kmol/h
n_{H2}=154453,15145363184274 kmol/h
n_{CO2}=1,4782281785004656358e-06 kmol/h
n_{H2O}=2279,0951867514982041 kmol/h
n_{CH4}=5224,2128658648989585 kmol/h
n_{NH3}=9361,0465534256654792 kmol/h
n_{AR}=439,73642482993273006 kmol/h
n_{O2}=-2,0572883921011577355e-18 kmol/h
n_{N2}=20567,113843935800105 kmol/h
n_T=192324,35634176110034 kmol/h
y_{CO}=6,1579619512296064652e-11
y_{H2}=0,8030867976969490174
y_{CO2}=7,6861205029780435254e-12
y_{H2O}=0,011850268110095932977
y_{CH4}=0,02716355309975119689
y_{NH3}=0,048673224398011506742
y_{AR}=0,0022864312830379084421
y_{O2}=-1,0696972714393742298e-23
y_{N2}=0,10693972534288875842
T: 573.15 °K
p: 180 bar
H: 1148287.561898 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,7075008816189236689e-08 kW (adiabat)
n_{CO}=1,1415449827852350214e-05 kmol/h
n_{H2}=126168,53123252748628 kmol/h
n_{CO2}=1,3356175044593581862e-06 kmol/h
n_{H2O}=2279,0951874645306816 kmol/h
n_{CH4}=5224,2128664353203931 kmol/h
n_{NH3}=28217,460032925988344 kmol/h
n_{AR}=439,73642482993273006 kmol/h
n_{O2}=3,8057875042321502979e-18 kmol/h
n_{N2}=11138,907104185636854 kmol/h
n_T=173467,94286111995461 kmol/h
y_{CO}=6,5807258906573107749e-11
y_{H2}=0,72733053238279987696
y_{CO2}=7,6995062167115565759e-12
y_{H2O}=0,013138422868651848663
y_{CH4}=0,030116301492189096606
y_{NH3}=0,16266671275116895146
y_{AR}=0,0025349722696716924485
y_{O2}=2,1939428354662041352e-23
y_{N2}=0,064213058162011810159
T: 740.361 °K
p: 180 bar
H: 1273109.386061 J/kmol
Gesamtfehler: 16.000118169647454
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -797231,60372038092464 kW
Dampfphase (zum Splitter):
n_{CO}=1,1389328897908098577e-05 kmol/h
n_{H2}=125972,87193634154391 kmol/h
n_{CO2}=1,1981602538044159085e-06 kmol/h
n_{H2O}=33,570817361217230257 kmol/h
n_{CH4}=5175,3562652183400132 kmol/h
n_{NH3}=13349,187393695385254 kmol/h
n_{AR}=436,58221488704089097 kmol/h
n_{O2}=3,7773750469474539165e-18 kmol/h
n_{N2}=11115,294096451414589 kmol/h
n_T=156082,86273654244724 kmol/h
y_{CO}=7,2969759127505268517e-11
y_{H2}=0,80708970688196235432
y_{CO2}=7,6764369437357412387e-12
y_{H2O}=0,00021508330108997261612
y_{CH4}=0,033157748227059302693
y_{NH3}=0,085526284945972072538
y_{AR}=0,0027971181924082827962
y_{O2}=2,420108768310579895e-23
y_{N2}=0,071214058362860502283
H2/N2 Verhältnis: 11.333291844842748
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6582610.063677 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=2,6120929944253579041e-08 kmol/h
n_{H2}=195,65929618595151851 kmol/h
n_{CO2}=1,3745725065494233064e-07 kmol/h
n_{H2O}=2245,5243701033132311 kmol/h
n_{CH4}=48,856601216979498759 kmol/h
n_{NH3}=14868,272639230604909 kmol/h
n_{AR}=3,1542099428918048964 kmol/h
n_{O2}=2,8412457284696194868e-20 kmol/h
n_{N2}=23,613007734223327105 kmol/h
n_T=17385,080124577543756 kmol/h
x_{CO}=1,5024912027412792547e-12
x_{H2}=0,011254437414033001408
x_{CO2}=7,906621636473879446e-12
x_{H2O}=0,12916387811696614096
x_{CH4}=0,0028102603422241294318
x_{NH3}=0,85523175813720853089
x_{AR}=0,00018143200494424182754
x_{O2}=1,6343011986795590085e-24
x_{N2}=0,0013582340470515031489
T: 294.15 °K
p: 180 bar
H: -70875803.514178 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=9,1114631183264788617e-06 kmol/h
n_{H2}=100778,29754907323513 kmol/h
n_{CO2}=9,5852820304353276918e-07 kmol/h
n_{H2O}=26,856653888973784916 kmol/h
n_{CH4}=4140,2850121746723744 kmol/h
n_{NH3}=10679,349914956308567 kmol/h
n_{AR}=349,26577190963274688 kmol/h
n_{O2}=3,0219000375579632102e-18 kmol/h
n_{N2}=8892,2352771611331264 kmol/h
n_T=124866,29018923395779 kmol/h
y_{CO}=7,2969759128089115858e-11
y_{H2}=0,80708970688842007757
y_{CO2}=7,6764369437971626304e-12
y_{H2O}=0,00021508330109169354312
y_{CH4}=0,033157748227324604362
y_{NH3}=0,085526284946656386254
y_{AR}=0,0027971181924306628974
y_{O2}=2,4201087683299435196e-23
y_{N2}=0,071214058363430310372
T: 294.15 °K
p: 180 bar
H: -6582610.063677 J/kmol
========================================
Abgas:
n_{CO}=2,2778657795816192919e-06 kmol/h
n_{H2}=25194,574387268301507 kmol/h
n_{CO2}=2,3963205076088308642e-07 kmol/h
n_{H2O}=6,7141634722434444527 kmol/h
n_{CH4}=1035,0712530436678662 kmol/h
n_{NH3}=2669,8374787390766869 kmol/h
n_{AR}=87,31644297740817251 kmol/h
n_{O2}=7,5547500938949060996e-19 kmol/h
n_{N2}=2223,0588192902828268 kmol/h
n_T=31216,572547308478534 kmol/h
y_{CO}=7,2969759128089128783e-11
y_{H2}=0,80708970688842007757
y_{CO2}=7,6764369437971626304e-12
y_{H2O}=0,00021508330109169354312
y_{CH4}=0,033157748227324611301
y_{NH3}=0,085526284946656400132
y_{AR}=0,0027971181924306633311
y_{O2}=2,4201087683299438134e-23
y_{N2}=0,07121405836343032425
T: 294.15 °K
p: 180 bar
H: -6582610.063677 J/kmol
========================================
========================================
==============4. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 424.002 °K
Vorwärmer (auf T= 573.15 °K), Q: 260986,5522484894318 kW
n_{CO}=9,3013255651859581239e-06 kmol/h
n_{H2}=167250,59821185673354 kmol/h
n_{CO2}=1,0920650754975201931e-06 kmol/h
n_{H2O}=2280,6686324056008743 kmol/h
n_{CH4}=5925,5324583124775017 kmol/h
n_{NH3}=10732,42067883994423 kmol/h
n_{AR}=499,26315407172825189 kmol/h
n_{O2}=3,0219000375579632102e-18 kmol/h
n_{N2}=20563,384145353087661 kmol/h
n_T=207251,86729123297846 kmol/h
y_{CO}=4,4879332991078030407e-11
y_{H2}=0,80699199673233368291
y_{CO2}=5,2692653136048058756e-12
y_{H2O}=0,011004333337082923897
y_{CH4}=0,02859097259657421633
y_{NH3}=0,051784434172352275527
y_{AR}=0,0024089681825165765519
y_{O2}=1,4580809702966634234e-23
y_{N2}=0,099219294928991674798
T: 573.15 °K
p: 180 bar
H: 1115564.882480 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -1,3648986816406249735e-07 kW (adiabat)
n_{CO}=9,4259879808717291053e-06 kmol/h
n_{H2}=137487,35083117589238 kmol/h
n_{CO2}=1,0503081890168259733e-06 kmol/h
n_{H2O}=2280,6686323644521508 kmol/h
n_{CH4}=5925,5324582295725122 kmol/h
n_{NH3}=30574,58559943180444 kmol/h
n_{AR}=499,26315407172825189 kmol/h
n_{O2}=-1,2301734521638306625e-18 kmol/h
n_{N2}=10642,301685057156647 kmol/h
n_T=187409,70237080688821 kmol/h
y_{CO}=5,0296157891663297785e-11
y_{H2}=0,73361917281713007188
y_{CO2}=5,6043426553161967422e-12
y_{H2O}=0,012169426681292866421
y_{CH4}=0,031618066638328973239
y_{NH3}=0,16314302414790268769
y_{AR}=0,0026640197799572369261
y_{O2}=-6,564086259151205139e-24
y_{N2}=0,056786289879487708565
T: 735.959 °K
p: 180 bar
H: 1233676.282781 J/kmol
Gesamtfehler: 16.00754316297337
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -852278,56268348859157 kW
Dampfphase (zum Splitter):
n_{CO}=9,4035098746480817169e-06 kmol/h
n_{H2}=137266,83372996724211 kmol/h
n_{CO2}=9,4061983451885722642e-07 kmol/h
n_{H2O}=34,892867303371929211 kmol/h
n_{CH4}=5868,2079063213486734 kmol/h
n_{NH3}=14497,005679866177161 kmol/h
n_{AR}=495,58266714414287435 kmol/h
n_{O2}=-1,2207402592426677816e-18 kmol/h
n_{N2}=10618,793018300790209 kmol/h
n_T=168781,31587924718042 kmol/h
y_{CO}=5,5714163772041373182e-11
y_{H2}=0,81328216345252424269
y_{CO2}=5,5730092493336489365e-12
y_{H2O}=0,00020673418216503173291
y_{CH4}=0,034768113257647975667
y_{NH3}=0,085892242303037436013
y_{AR}=0,0029362412809596969386
y_{O2}=-7,232674143293282461e-24
y_{N2}=0,062914505452695182464
H2/N2 Verhältnis: 12.926783062198961
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6718019.680016 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=2,2478106223647160044e-08 kmol/h
n_{H2}=220,51710120865763542 kmol/h
n_{CO2}=1,0968835449796886603e-07 kmol/h
n_{H2O}=2245,7757650610788005 kmol/h
n_{CH4}=57,324551908223369878 kmol/h
n_{NH3}=16077,57991956564365 kmol/h
n_{AR}=3,6804869275853624444 kmol/h
n_{O2}=-9,4331929211625844098e-21 kmol/h
n_{N2}=23,508666756364807071 kmol/h
n_T=18628,386491559718706 kmol/h
x_{CO}=1,2066587858161427348e-12
x_{H2}=0,0118376919722982029
x_{CO2}=5,8882369955814897974e-12
x_{H2O}=0,1205566443597057974
x_{CH4}=0,0030772687660966116865
x_{NH3}=0,86306884003403938621
x_{AR}=0,00019757411247484329801
x_{O2}=-5,0638808284680300864e-25
x_{N2}=0,0012619808360256441152
T: 294.15 °K
p: 180 bar
H: -69174429.007357 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=7,5228078997184662206e-06 kmol/h
n_{H2}=109813,46698397380533 kmol/h
n_{CO2}=7,5249586761508582349e-07 kmol/h
n_{H2O}=27,914293842697546211 kmol/h
n_{CH4}=4694,5663250570787568 kmol/h
n_{NH3}=11597,604543892943184 kmol/h
n_{AR}=396,46613371531429948 kmol/h
n_{O2}=-9,765922073941342253e-19 kmol/h
n_{N2}=8495,0344146406332584 kmol/h
n_T=135025,05270339775598 kmol/h
y_{CO}=5,5714163772580869425e-11
y_{H2}=0,81328216346039960971
y_{CO2}=5,5730092493876152013e-12
y_{H2O}=0,0002067341821670336038
y_{CH4}=0,03476811325798464386
y_{NH3}=0,085892242303869159592
y_{AR}=0,0029362412809881294901
y_{O2}=-7,2326741433633184144e-24
y_{N2}=0,062914505453304417348
T: 294.15 °K
p: 180 bar
H: -6718019.680016 J/kmol
========================================
Abgas:
n_{CO}=1,8807019749296159199e-06 kmol/h
n_{H2}=27453,366745993444056 kmol/h
n_{CO2}=1,8812396690377140293e-07 kmol/h
n_{H2O}=6,9785734606743847763 kmol/h
n_{CH4}=1173,6415812642694618 kmol/h
n_{NH3}=2899,4011359732353412 kmol/h
n_{AR}=99,116533428828546448 kmol/h
n_{O2}=-2,4414805184853350818e-19 kmol/h
n_{N2}=2123,7586036601574051 kmol/h
n_T=33756,263175849431718 kmol/h
y_{CO}=5,5714163772580869425e-11
y_{H2}=0,81328216346039960971
y_{CO2}=5,5730092493876143935e-12
y_{H2O}=0,0002067341821670336038
y_{CH4}=0,034768113257984650799
y_{NH3}=0,085892242303869159592
y_{AR}=0,0029362412809881294901
y_{O2}=-7,2326741433633184144e-24
y_{N2}=0,062914505453304403471
T: 294.15 °K
p: 180 bar
H: -6718019.680016 J/kmol
========================================
========================================
==============5. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 417.892 °K
Vorwärmer (auf T= 573.15 °K), Q: 285245,74253748107003 kW
n_{CO}=7,7126703465779446357e-06 kmol/h
n_{H2}=176285,76764675727463 kmol/h
n_{CO2}=8,8603274006907345918e-07 kmol/h
n_{H2O}=2281,7262723593244118 kmol/h
n_{CH4}=6479,8137711948847937 kmol/h
n_{NH3}=11650,675307776578848 kmol/h
n_{AR}=546,4635158774096908 kmol/h
n_{O2}=-9,765922073941342253e-19 kmol/h
n_{N2}=20166,183282832585974 kmol/h
n_T=217410,62980539671844 kmol/h
y_{CO}=3,5475129957912000018e-11
y_{H2}=0,81084244962884233221
y_{CO2}=4,0753883140955775828e-12
y_{H2O}=0,010495007877037510965
y_{CH4}=0,029804493814285609038
y_{NH3}=0,05358834256726567602
y_{AR}=0,0025135087293870900238
y_{O2}=-4,4919248349001036526e-24
y_{N2}=0,092756197343631482943
T: 573.15 °K
p: 180 bar
H: 1073457.757262 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 8,7205039130316841028e-08 kW (adiabat)
n_{CO}=8,0137631826926585416e-06 kmol/h
n_{H2}=145694,88183044316247 kmol/h
n_{CO2}=8,6890627843357590429e-07 kmol/h
n_{H2O}=2281,7262720924850328 kmol/h
n_{CH4}=6479,8137709109178104 kmol/h
n_{NH3}=32044,599185875824332 kmol/h
n_{AR}=546,4635158774096908 kmol/h
n_{O2}=-2,3259542049764365434e-18 kmol/h
n_{N2}=9969,2213437829614122 kmol/h
n_T=197016,70592786543421 kmol/h
y_{CO}=4,0675551572904535411e-11
y_{H2}=0,73950521680017866633
y_{CO2}=4,4103177664117084943e-12
y_{H2O}=0,011581384742712644981
y_{CH4}=0,032889666591438188048
y_{NH3}=0,16264914711145586623
y_{AR}=0,0027736912628997497168
y_{O2}=-1,180587297925917054e-23
y_{N2}=0,050600893446229040784
T: 732.35 °K
p: 180 bar
H: 1184575.318001 J/kmol
Gesamtfehler: 16.003079270412798
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -887471,69218424276914 kW
Dampfphase (zum Splitter):
n_{CO}=7,9944344313467161274e-06 kmol/h
n_{H2}=145459,48058334793313 kmol/h
n_{CO2}=7,7824495928301980864e-07 kmol/h
n_{H2O}=35,902684810546439564 kmol/h
n_{CH4}=6416,6363819221378435 kmol/h
n_{NH3}=15284,905929073189327 kmol/h
n_{AR}=542,41755034371090005 kmol/h
n_{O2}=-2,3080459559910735086e-18 kmol/h
n_{N2}=9946,9495983218330366 kmol/h
n_T=177686,29273659206228 kmol/h
y_{CO}=4,4991846631255062298e-11
y_{H2}=0,818630848457099769
y_{CO2}=4,3798817978059898009e-12
y_{H2O}=0,0002020565810525114356
y_{CH4}=0,036112163088357379648
y_{NH3}=0,086021862989771866181
y_{AR}=0,0030526696346991279325
y_{O2}=-1,2989442913267568212e-23
y_{N2}=0,055980399191432266004
H2/N2 Verhältnis: 14.623526453566095
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6823508.199507 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,9328751345942023852e-08 kmol/h
n_{H2}=235,40124709522913804 kmol/h
n_{CO2}=9,0661319150556347108e-08 kmol/h
n_{H2O}=2245,8235872819386714 kmol/h
n_{CH4}=63,177388988780435852 kmol/h
n_{NH3}=16759,693256802631367 kmol/h
n_{AR}=4,0459655336988644692 kmol/h
n_{O2}=-1,790824898536326352e-20 kmol/h
n_{N2}=22,27174546112967235 kmol/h
n_T=19330,413191273397388 kmol/h
x_{CO}=9,9991402957322677675e-13
x_{H2}=0,012177765926869895188
x_{CO2}=4,6900869764300326418e-12
x_{H2O}=0,11618083717245096531
x_{CH4}=0,0032682896308741274209
x_{NH3}=0,86701164078760151188
x_{AR}=0,0002093056932601381143
x_{O2}=-9,2642867017453019144e-25
x_{N2}=0,001152160858768708435
T: 294.15 °K
p: 180 bar
H: -68311705.897906 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=6,3955475450773739183e-06 kmol/h
n_{H2}=116367,58446667836688 kmol/h
n_{CO2}=6,2259596742641582574e-07 kmol/h
n_{H2O}=28,72214784843714952 kmol/h
n_{CH4}=5133,3091055377108205 kmol/h
n_{NH3}=12227,924743258550734 kmol/h
n_{AR}=433,93404027496876552 kmol/h
n_{O2}=-1,846436764792858961e-18 kmol/h
n_{N2}=7957,559678657466975 kmol/h
n_T=142149,03418927366147 kmol/h
y_{CO}=4,4991846631624682785e-11
y_{H2}=0,81863084846382505599
y_{CO2}=4,3798817978419721575e-12
y_{H2O}=0,00020205658105417137623
y_{CH4}=0,036112163088654052057
y_{NH3}=0,08602186299047856477
y_{AR}=0,0030526696347242068298
y_{O2}=-1,2989442913374279589e-23
y_{N2}=0,055980399191892162014
T: 294.15 °K
p: 180 bar
H: -6823508.199507 J/kmol
========================================
Abgas:
n_{CO}=1,5988868862693430561e-06 kmol/h
n_{H2}=29091,896116669584444 kmol/h
n_{CO2}=1,556489918566039035e-07 kmol/h
n_{H2O}=7,1805369621092856036 kmol/h
n_{CH4}=1283,3272763844272504 kmol/h
n_{NH3}=3056,9811858146372288 kmol/h
n_{AR}=108,48351006874216296 kmol/h
n_{O2}=-4,6160919119821464394e-19 kmol/h
n_{N2}=1989,3899196643660616 kmol/h
n_T=35537,258547318408091 kmol/h
y_{CO}=4,4991846631624676323e-11
y_{H2}=0,81863084846382494497
y_{CO2}=4,3798817978419713497e-12
y_{H2O}=0,00020205658105417137623
y_{CH4}=0,036112163088654045118
y_{NH3}=0,08602186299047856477
y_{AR}=0,0030526696347242063961
y_{O2}=-1,2989442913374279589e-23
y_{N2}=0,055980399191892162014
T: 294.15 °K
p: 180 bar
H: -6823508.199507 J/kmol
========================================
========================================
==============6. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 413.935 °K
Vorwärmer (auf T= 573.15 °K), Q: 302291,0769322552369 kW
n_{CO}=6,5854099919368523335e-06 kmol/h
n_{H2}=182839,88512946185074 kmol/h
n_{CO2}=7,5613283988040346143e-07 kmol/h
n_{H2O}=2282,5341263650643668 kmol/h
n_{CH4}=6918,5565516755159479 kmol/h
n_{NH3}=12280,995507142186398 kmol/h
n_{AR}=583,93142243706427053 kmol/h
n_{O2}=-1,846436764792858961e-18 kmol/h
n_{N2}=19628,708546849422419 kmol/h
n_T=224534,61129127271124 kmol/h
y_{CO}=2,9329153105015379686e-11
y_{H2}=0,81430601757996556866
y_{CO2}=3,3675558326262957157e-12
y_{H2O}=0,010165622632691117405
y_{CH4}=0,030812873400175116306
y_{NH3}=0,054695333768435945576
y_{AR}=0,0026006298943354070816
y_{O2}=-8,2233948440029519129e-24
y_{N2}=0,087419522691699863559
T: 573.15 °K
p: 180 bar
H: 1032759.228422 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 7,2415669759114588536e-08 kW (adiabat)
n_{CO}=6,9559609032677684277e-06 kmol/h
n_{H2}=151808,07395492689102 kmol/h
n_{CO2}=7,4306458255561420917e-07 kmol/h
n_{H2O}=2282,5341260206496372 kmol/h
n_{CH4}=6918,5565513180335984 kmol/h
n_{NH3}=32968,869624205079162 kmol/h
n_{AR}=583,93142243706427053 kmol/h
n_{O2}=5,0059128762846944578e-14 kmol/h
n_{N2}=9284,7714883179760363 kmol/h
n_T=203846,73717492466676 kmol/h
y_{CO}=3,4123484141415168102e-11
y_{H2}=0,74471672227285912182
y_{CO2}=3,6452120492759063134e-12
y_{H2O}=0,011197305179635838601
y_{CH4}=0,033939991619199139095
y_{NH3}=0,16173361458277293878
y_{AR}=0,0028645610448794272748
y_{O2}=2,4557238176390469688e-19
y_{N2}=0,045547805262885029953
T: 729.292 °K
p: 180 bar
H: 1137571.271069 J/kmol
Gesamtfehler: 0.589937322571693
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -910357,71156675636303 kW
Dampfphase (zum Splitter):
n_{CO}=6,939234763811500325e-06 kmol/h
n_{H2}=151564,08318182994844 kmol/h
n_{CO2}=6,6616172403957892253e-07 kmol/h
n_{H2O}=36,728313742070874071 kmol/h
n_{CH4}=6851,4164488788337621 kmol/h
n_{NH3}=15842,975130997903761 kmol/h
n_{AR}=579,63638275600897032 kmol/h
n_{O2}=4,96762894351433701e-14 kmol/h
n_{N2}=9264,0933258398581529 kmol/h
n_T=184138,93279165000422 kmol/h
y_{CO}=3,7684777784597817469e-11
y_{H2}=0,82309634840720247162
y_{CO2}=3,6177125278936653767e-12
y_{H2O}=0,00019945979475879415158
y_{CH4}=0,03720786443661395354
y_{NH3}=0,08603816091828417334
y_{AR}=0,0031478209087179472025
y_{O2}=2,6977613414803829961e-19
y_{N2}=0,050310345483727793303
H2/N2 Verhältnis: 16.360379569912155
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6905691.027152 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,6726139456268357447e-08 kmol/h
n_{H2}=243,99077309693231541 kmol/h
n_{CO2}=7,6902858516035366052e-08 kmol/h
n_{H2O}=2245,8058122785769228 kmol/h
n_{CH4}=67,140102439199381479 kmol/h
n_{NH3}=17125,894493207182677 kmol/h
n_{AR}=4,2950396810552611271 kmol/h
n_{O2}=3,8283932770358177511e-16 kmol/h
n_{N2}=20,678162478118956358 kmol/h
n_T=19707,804383274691645 kmol/h
x_{CO}=8,4870638719811508408e-13
x_{H2}=0,012380413788022532479
x_{CO2}=3,9021525192349204252e-12
x_{H2O}=0,11395515039623610454
x_{CH4}=0,0034067773933290608837
x_{NH3}=0,86899048527416289378
x_{AR}=0,00021793598099021318126
x_{O2}=1,9425772668115265425e-20
x_{N2}=0,0010492372502683498369
T: 294.15 °K
p: 180 bar
H: -67874767.751154 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=5,5513878110492005988e-06 kmol/h
n_{H2}=121251,26654546397913 kmol/h
n_{CO2}=5,329293792316631592e-07 kmol/h
n_{H2O}=29,38265099365670352 kmol/h
n_{CH4}=5481,1331591030675554 kmol/h
n_{NH3}=12674,380104798325192 kmol/h
n_{AR}=463,70910620480725584 kmol/h
n_{O2}=3,9741031548114699867e-14 kmol/h
n_{N2}=7411,2746606718874318 kmol/h
n_T=147311,14623332003248 kmol/h
y_{CO}=3,7684777784951773223e-11
y_{H2}=0,82309634841493339863
y_{CO2}=3,6177125279276448092e-12
y_{H2O}=0,00019945979476066757162
y_{CH4}=0,037207864436963430932
y_{NH3}=0,086038160919092290801
y_{AR}=0,0031478209087475129621
y_{O2}=2,6977613415057219749e-19
y_{N2}=0,050310345484200331978
T: 294.15 °K
p: 180 bar
H: -6905691.027152 J/kmol
========================================
Abgas:
n_{CO}=1,3878469527622997262e-06 kmol/h
n_{H2}=30312,816636365983868 kmol/h
n_{CO2}=1,3323234480791576333e-07 kmol/h
n_{H2O}=7,3456627484141723272 kmol/h
n_{CH4}=1370,2832897757664341 kmol/h
n_{NH3}=3168,5950261995803885 kmol/h
n_{AR}=115,92727655120178554 kmol/h
n_{O2}=9,9352578870286718112e-15 kmol/h
n_{N2}=1852,8186651679711758 kmol/h
n_T=36827,786558330000844 kmol/h
y_{CO}=3,768477778495176676e-11
y_{H2}=0,82309634841493317658
y_{CO2}=3,6177125279276448092e-12
y_{H2O}=0,00019945979476066754451
y_{CH4}=0,037207864436963423993
y_{NH3}=0,086038160919092276924
y_{AR}=0,0031478209087475129621
y_{O2}=2,6977613415057214934e-19
y_{N2}=0,050310345484200331978
T: 294.15 °K
p: 180 bar
H: -6905691.027152 J/kmol
========================================
========================================
==============7. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 411.221 °K
Vorwärmer (auf T= 573.15 °K), Q: 314660,33277805539547 kW
n_{CO}=5,741250257908679014e-06 kmol/h
n_{H2}=187723,56720824746299 kmol/h
n_{CO2}=6,6646625168565068901e-07 kmol/h
n_{H2O}=2283,1946295102839031 kmol/h
n_{CH4}=7266,3806052408735923 kmol/h
n_{NH3}=12727,450868681957218 kmol/h
n_{AR}=613,706488366902704 kmol/h
n_{O2}=3,9741031548114699867e-14 kmol/h
n_{N2}=19082,423528863841057 kmol/h
n_T=229696,72333531905315 kmol/h
y_{CO}=2,4994915793933234322e-11
y_{H2}=0,817267066253279717
y_{CO2}=2,9015052631496218456e-12
y_{H2O}=0,0099400400508857025828
y_{CH4}=0,031634672448649453491
y_{NH3}=0,055409805955751463558
y_{AR}=0,0026718121158001597974
y_{O2}=1,7301523056599897693e-19
y_{N2}=0,083076603147737002053
T: 573.15 °K
p: 180 bar
H: 997355.770814 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 5,5779351128472228824e-09 kW (adiabat)
n_{CO}=6,1482859178481210851e-06 kmol/h
n_{H2}=156472,96028372136061 kmol/h
n_{CO2}=6,5169576953008502089e-07 kmol/h
n_{H2O}=2283,1946291327890322 kmol/h
n_{CH4}=7266,3806048486085274 kmol/h
n_{NH3}=33561,18881914071244 kmol/h
n_{AR}=613,706488366902704 kmol/h
n_{O2}=-3,006133760808191181e-18 kmol/h
n_{N2}=8665,5545536344652646 kmol/h
n_T=208862,98538564477349 kmol/h
y_{CO}=2,9436934009613633379e-11
y_{H2}=0,74916558333593463725
y_{CO2}=3,1202070980973174102e-12
y_{H2O}=0,010931542632683800137
y_{CH4}=0,034790178793202432284
y_{NH3}=0,16068519157271121678
y_{AR}=0,0029383209630646357595
y_{O2}=-1,4392850677958393565e-23
y_{N2}=0,041489182669846351448
T: 726.69 °K
p: 180 bar
H: 1096840.362272 J/kmol
Gesamtfehler: 96224.00437943684
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -925635,8663852653699 kW
Dampfphase (zum Splitter):
n_{CO}=6,133644040775956409e-06 kmol/h
n_{H2}=156224,19253459671745 kmol/h
n_{CO2}=5,8499310388878995672e-07 kmol/h
n_{H2O}=37,423740040224231507 kmol/h
n_{CH4}=7196,5864789821671366 kmol/h
n_{NH3}=16251,67375153015746 kmol/h
n_{AR}=609,24330763943464717 kmol/h
n_{O2}=-2,9834042582861380334e-18 kmol/h
n_{N2}=8646,4417651852181734 kmol/h
n_T=188965,56158469253569 kmol/h
y_{CO}=3,2459057562025827028e-11
y_{H2}=0,8267336715907581679
y_{CO2}=3,0957656991963635274e-12
y_{H2O}=0,00019804529315304946185
y_{CH4}=0,038084116590148153758
y_{NH3}=0,086003362809010802659
y_{AR}=0,0032240970392937349197
y_{O2}=-1,578808452312010402e-23
y_{N2}=0,045756706632644104926
H2/N2 Verhältnis: 18.068032697985817
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -6969375.590266 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,4641877072166044275e-08 kmol/h
n_{H2}=248,76774912464611589 kmol/h
n_{CO2}=6,6702665641295156809e-08 kmol/h
n_{H2O}=2245,7708890925632659 kmol/h
n_{CH4}=69,794125866440893446 kmol/h
n_{NH3}=17309,515067610547703 kmol/h
n_{AR}=4,4631807274679839992 kmol/h
n_{O2}=-2,2729502522052906873e-20 kmol/h
n_{N2}=19,11278844924636644 kmol/h
n_T=19897,423800952255988 kmol/h
x_{CO}=7,3586798069695869444e-13
x_{H2}=0,012502510457410905692
x_{CO2}=3,352326729055306108e-12
x_{H2O}=0,11286742001174868144
x_{CH4}=0,003507696602881628118
x_{NH3}=0,86993749755350391339
x_{AR}=0,00022430947707182083309
x_{O2}=-1,1423339398843317498e-24
x_{N2}=0,00096056598292109903522
T: 294.15 °K
p: 180 bar
H: -67662795.100688 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=4,9069152326207647884e-06 kmol/h
n_{H2}=124979,35402767737105 kmol/h
n_{CO2}=4,6799448311103199714e-07 kmol/h
n_{H2O}=29,938992032179392311 kmol/h
n_{CH4}=5757,2691831857337093 kmol/h
n_{NH3}=13001,33900122412706 kmol/h
n_{AR}=487,39464611154778595 kmol/h
n_{O2}=-2,3867234066289105037e-18 kmol/h
n_{N2}=6917,1534121481745387 kmol/h
n_T=151172,4492677540693 kmol/h
y_{CO}=3,2459057562332142349e-11
y_{H2}=0,82673367159856003816
y_{CO2}=3,0957656992255781895e-12
y_{H2O}=0,00019804529315491843666
y_{CH4}=0,038084116590507546829
y_{NH3}=0,086003362809822417323
y_{AR}=0,0032240970393241606684
y_{O2}=-1,5788084523269094991e-23
y_{N2}=0,045756706633075912294
T: 294.15 °K
p: 180 bar
H: -6969375.590266 J/kmol
========================================
Abgas:
n_{CO}=1,2267288081551909853e-06 kmol/h
n_{H2}=31244,838506919335487 kmol/h
n_{CO2}=1,1699862077775797282e-07 kmol/h
n_{H2O}=7,484748008044844525 kmol/h
n_{CH4}=1439,3172957964331999 kmol/h
n_{NH3}=3250,3347503060308554 kmol/h
n_{AR}=121,84866152788691807 kmol/h
n_{O2}=-5,9668085165722743334e-19 kmol/h
n_{N2}=1729,2883530370431799 kmol/h
n_T=37793,112316938502772 kmol/h
y_{CO}=3,2459057562332148811e-11
y_{H2}=0,82673367159856014919
y_{CO2}=3,0957656992255789973e-12
y_{H2O}=0,00019804529315491843666
y_{CH4}=0,038084116590507560707
y_{NH3}=0,086003362809822417323
y_{AR}=0,0032240970393241611021
y_{O2}=-1,5788084523269094991e-23
y_{N2}=0,045756706633075919233
T: 294.15 °K
p: 180 bar
H: -6969375.590266 J/kmol
========================================
========================================
==============8. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 409.269 °K
Vorwärmer (auf T= 573.15 °K), Q: 323920,9679593910696 kW
n_{CO}=5,0967776794802440506e-06 kmol/h
n_{H2}=191451,65469046085491 kmol/h
n_{CO2}=6,0153135556501957989e-07 kmol/h
n_{H2O}=2283,7509705488068903 kmol/h
n_{CH4}=7542,5166293235397461 kmol/h
n_{NH3}=13054,409765107762723 kmol/h
n_{AR}=637,39202827364317727 kmol/h
n_{O2}=-2,3867234066289101185e-18 kmol/h
n_{N2}=18588,302280340129073 kmol/h
n_T=233558,02636975303176 kmol/h
y_{CO}=2,1822318670441989557e-11
y_{H2}=0,819717727822240394
y_{CO2}=2,5755113832513570178e-12
y_{H2O}=0,0097780881524205422173
y_{CH4}=0,032293973136177919758
y_{NH3}=0,055893646508388100669
y_{AR}=0,0027290521254215768104
y_{O2}=-1,0218974032818780436e-23
y_{N2}=0,079587512230953699754
T: 573.15 °K
p: 180 bar
H: 968219.014429 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -4,5943790011935763167e-08 kW (adiabat)
n_{CO}=5,5284276875683146783e-06 kmol/h
n_{H2}=160104,08192904430325 kmol/h
n_{CO2}=5,8376502017802110605e-07 kmol/h
n_{H2O}=2283,7509701526892059 kmol/h
n_{CH4}=7542,5166289096559922 kmol/h
n_{NH3}=33952,791606868042436 kmol/h
n_{AR}=637,39202827364317727 kmol/h
n_{O2}=1,8336469416135449617e-18 kmol/h
n_{N2}=8139,1113594599846692 kmol/h
n_T=212659,64452882052865 kmol/h
y_{CO}=2,5996599871204426875e-11
y_{H2}=0,752865369843813248
y_{CO2}=2,7450672245382544419e-12
y_{H2O}=0,010738995521283238241
y_{CH4}=0,035467550252052934545
y_{NH3}=0,15965789692772019981
y_{AR}=0,0029972401660215380707
y_{O2}=8,6224490108420254039e-24
y_{N2}=0,038272947260367208566
T: 724.491 °K
p: 180 bar
H: 1063367.347409 J/kmol
Gesamtfehler: 0.16543579228791164
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -936193,62871653016191 kW
Dampfphase (zum Splitter):
n_{CO}=5,5154195207669665593e-06 kmol/h
n_{H2}=159852,75520118678105 kmol/h
n_{CO2}=5,2471080801774635695e-07 kmol/h
n_{H2O}=38,013850484397202933 kmol/h
n_{CH4}=7470,9459138335614625 kmol/h
n_{NH3}=16560,476408081020054 kmol/h
n_{AR}=632,81528700580122404 kmol/h
n_{O2}=1,8199586079764755726e-18 kmol/h
n_{N2}=8121,3750320819744957 kmol/h
n_T=192676,38169871366699 kmol/h
y_{CO}=2,8625301513814857381e-11
y_{H2}=0,82964374663048279235
y_{CO2}=2,7232751797957065516e-12
y_{H2O}=0,00019729377388605777205
y_{CH4}=0,03877458071351750496
y_{NH3}=0,085949695867888642464
y_{AR}=0,0032843428001961606257
y_{O2}=9,4456756552844894573e-24
y_{N2}=0,042150340173540676303
H2/N2 Verhältnis: 19.68296680915711
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7018438.699071 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,3008166801348694807e-08 kmol/h
n_{H2}=251,32672785752635036 kmol/h
n_{CO2}=5,9054212160274788802e-08 kmol/h
n_{H2O}=2245,7371196682929622 kmol/h
n_{CH4}=71,570715076093819107 kmol/h
n_{NH3}=17392,315198787029658 kmol/h
n_{AR}=4,5767412678421255379 kmol/h
n_{O2}=1,3688333637069777224e-20 kmol/h
n_{N2}=17,736327378009796973 kmol/h
n_T=19983,262830106854381 kmol/h
x_{CO}=6,5095309575255492369e-13
x_{H2}=0,012576861447322024851
x_{CO2}=2,9551836788388511516e-12
x_{H2O}=0,11238090290654433046
x_{CH4}=0,0035815329904269783967
x_{NH3}=0,87034411488179885819
x_{AR}=0,00022902872804886039229
x_{O2}=6,8498992154840431229e-25
x_{N2}=0,00088755913037640520556
T: 294.15 °K
p: 180 bar
H: -67569354.341583 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=4,4123356166135734168e-06 kmol/h
n_{H2}=127882,20416094941902 kmol/h
n_{CO2}=4,1976864641419706438e-07 kmol/h
n_{H2O}=30,411080387517767321 kmol/h
n_{CH4}=5976,75673106684917 kmol/h
n_{NH3}=13248,381126464817498 kmol/h
n_{AR}=506,25222960464100197 kmol/h
n_{O2}=1,4559668863811805351e-18 kmol/h
n_{N2}=6497,1000256655806879 kmol/h
n_T=154141,10535897093359 kmol/h
y_{CO}=2,862530151407648233e-11
y_{H2}=0,82964374663806539356
y_{CO2}=2,723275179820596287e-12
y_{H2O}=0,00019729377388786096289
y_{CH4}=0,038774580713871888149
y_{NH3}=0,085949695868674194643
y_{AR}=0,0032843428002261782807
y_{O2}=9,4456756553708207012e-24
y_{N2}=0,042150340173925916754
T: 294.15 °K
p: 180 bar
H: -7018438.699071 J/kmol
========================================
Abgas:
n_{CO}=1,1030839041533931424e-06 kmol/h
n_{H2}=31970,551040237347479 kmol/h
n_{CO2}=1,0494216160354923963e-07 kmol/h
n_{H2O}=7,6027700968794391656 kmol/h
n_{CH4}=1494,1891827667120651 kmol/h
n_{NH3}=3312,0952816162034651 kmol/h
n_{AR}=126,56305740116020786 kmol/h
n_{O2}=3,6399172159529503749e-19 kmol/h
n_{N2}=1624,2750064163947172 kmol/h
n_T=38535,276339742726122 kmol/h
y_{CO}=2,862530151407648233e-11
y_{H2}=0,82964374663806528254
y_{CO2}=2,723275179820596287e-12
y_{H2O}=0,00019729377388786093579
y_{CH4}=0,038774580713871888149
y_{NH3}=0,085949695868674180765
y_{AR}=0,003284342800226177847
y_{O2}=9,4456756553708192318e-24
y_{N2}=0,042150340173925909815
T: 294.15 °K
p: 180 bar
H: -7018438.699071 J/kmol
========================================
========================================
==============9. Iteration==============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 407.811 °K
Vorwärmer (auf T= 573.15 °K), Q: 331043,48180804186268 kW
n_{CO}=4,602198063473052679e-06 kmol/h
n_{H2}=194354,50482373291743 kmol/h
n_{CO2}=5,5330551886818470007e-07 kmol/h
n_{H2O}=2284,2230589041450912 kmol/h
n_{CH4}=7762,0041772046542974 kmol/h
n_{NH3}=13301,451890348453162 kmol/h
n_{AR}=656,24961176673650698 kmol/h
n_{O2}=1,4559668863811805351e-18 kmol/h
n_{N2}=18168,248893857533403 kmol/h
n_T=236526,68246096995426 kmol/h
y_{CO}=1,9457416032681538677e-11
y_{H2}=0,82170224010901593559
y_{CO2}=2,3392942948814555234e-12
y_{H2O}=0,0096573588871144474405
y_{CH4}=0,032816611201932736896
y_{NH3}=0,056236580803281546737
y_{AR}=0,0027745267677147856557
y_{O2}=6,1556136975008494262e-24
y_{N2}=0,076812682209143723355
T: 573.15 °K
p: 180 bar
H: 945026.787302 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 2,3015975952148437402e-07 kW (adiabat)
n_{CO}=5,0524115276265334329e-06 kmol/h
n_{H2}=162972,7080634550075 kmol/h
n_{CO2}=5,3260063169812207087e-07 kmol/h
n_{H2O}=2284,2230584953413199 kmol/h
n_{CH4}=7762,004176775146334 kmol/h
n_{NH3}=34222,649731378929573 kmol/h
n_{AR}=656,24961176673650698 kmol/h
n_{O2}=-3,6952216952815242188e-30 kmol/h
n_{N2}=7707,6499733422961071 kmol/h
n_T=215605,4846207984956 kmol/h
y_{CO}=2,3433594634721782612e-11
y_{H2}=0,75588386979156541035
y_{CO2}=2,4702554883278900955e-12
y_{H2O}=0,010594457105359705168
y_{CH4}=0,036000958836584162626
y_{NH3}=0,15872810374730894623
y_{AR}=0,0030437519385044021526
y_{O2}=-1,7138811203159267858e-35
y_{N2}=0,035748858554773395302
T: 722.656 °K
p: 180 bar
H: 1036727.109384 J/kmol
Gesamtfehler: 0.8285675048828125
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -943780,57869952567853 kW
Dampfphase (zum Splitter):
n_{CO}=5,040666855377232494e-06 kmol/h
n_{H2}=162720,05796840137918 kmol/h
n_{CO2}=4,7931532359349217128e-07 kmol/h
n_{H2O}=38,51258103323274895 kmol/h
n_{CH4}=7689,2318914787574613 kmol/h
n_{NH3}=16799,928501576741837 kmol/h
n_{AR}=651,59533972266683577 kmol/h
n_{O2}=-3,6679755973518900485e-30 kmol/h
n_{N2}=7691,0569008599504741 kmol/h
n_T=195590,38318859270657 kmol/h
y_{CO}=2,5771547522716858085e-11
y_{H2}=0,8319430399091632955
y_{CO2}=2,4506078252679214499e-12
y_{H2O}=0,00019690426699428499515
y_{CH4}=0,039312934337852545319
y_{NH3}=0,085893428028230314752
y_{AR}=0,0033314283099922939804
y_{O2}=-1,875335350093189406e-35
y_{N2}=0,039322265110416226852
H2/N2 Verhältnis: 21.15704773295948
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7056077.601255 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,1744672249300588218e-08 kmol/h
n_{H2}=252,65009505365031828 kmol/h
n_{CO2}=5,32853081046298268e-08 kmol/h
n_{H2O}=2245,7104774621084289 kmol/h
n_{CH4}=72,772285296388488973 kmol/h
n_{NH3}=17422,721229802187736 kmol/h
n_{AR}=4,6542720440695886097 kmol/h
n_{O2}=-2,7246097929633956808e-32 kmol/h
n_{N2}=16,593072482346464369 kmol/h
n_T=20015,101432205781748 kmol/h
x_{CO}=5,8679054363672934594e-13
x_{H2}=0,012622973504878474971
x_{CO2}=2,6622552121391352588e-12
x_{H2O}=0,1122008042411880846
x_{CH4}=0,0036358689237409704334
x_{NH3}=0,87047878774783471467
x_{AR}=0,00023253801936750216508
x_{O2}=-1,3612770349603895919e-36
x_{N2}=0,00082902764894946889915
T: 294.15 °K
p: 180 bar
H: -67536058.461149 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=4,0325334843017866728e-06 kmol/h
n_{H2}=130176,04637472110335 kmol/h
n_{CO2}=3,834522588747937582e-07 kmol/h
n_{H2O}=30,810064826586195608 kmol/h
n_{CH4}=6151,385513183005969 kmol/h
n_{NH3}=13439,94280126139347 kmol/h
n_{AR}=521,27627177813349135 kmol/h
n_{O2}=-2,9343804778815120388e-30 kmol/h
n_{N2}=6152,8455206879598336 kmol/h
n_T=156472,30655087420018 kmol/h
y_{CO}=2,5771547522952119883e-11
y_{H2}=0,83194303991675788712
y_{CO2}=2,4506078252902920811e-12
y_{H2O}=0,00019690426699608246683
y_{CH4}=0,039312934338211417973
y_{NH3}=0,085893428029014409764
y_{AR}=0,0033314283100227054177
y_{O2}=-1,8753353501103087312e-35
y_{N2}=0,039322265110775182773
T: 294.15 °K
p: 180 bar
H: -7056077.601255 J/kmol
========================================
Abgas:
n_{CO}=1,0081333710754462447e-06 kmol/h
n_{H2}=32544,011593680264923 kmol/h
n_{CO2}=9,586306471869841308e-08 kmol/h
n_{H2O}=7,7025162066465471256 kmol/h
n_{CH4}=1537,8463782957510375 kmol/h
n_{NH3}=3359,9857003153474579 kmol/h
n_{AR}=130,31906794453334442 kmol/h
n_{O2}=-7,3359511947037783454e-31 kmol/h
n_{N2}=1538,211380171989731 kmol/h
n_T=39118,076637718535494 kmol/h
y_{CO}=2,5771547522952116652e-11
y_{H2}=0,83194303991675788712
y_{CO2}=2,450607825290292485e-12
y_{H2O}=0,00019690426699608249393
y_{CH4}=0,039312934338211424912
y_{NH3}=0,085893428029014423641
y_{AR}=0,0033314283100227058514
y_{O2}=-1,8753353501103089985e-35
y_{N2}=0,03932226511077519665
T: 294.15 °K
p: 180 bar
H: -7056077.601255 J/kmol
========================================
========================================
==============10. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 406.693 °K
Vorwärmer (auf T= 573.15 °K), Q: 336636,52769375318894 kW
n_{CO}=4,222395931161265935e-06 kmol/h
n_{H2}=196648,34703750457265 kmol/h
n_{CO2}=5,1698913132878139389e-07 kmol/h
n_{H2O}=2284,6220433432135906 kmol/h
n_{CH4}=7936,6329593208129154 kmol/h
n_{NH3}=13493,013565145029133 kmol/h
n_{AR}=671,27365394022899636 kmol/h
n_{O2}=0 kmol/h
n_{N2}=17823,994388879913458 kmol/h
n_T=238857,88365287316265 kmol/h
y_{CO}=1,7677440101987924541e-11
y_{H2}=0,8232859808943515656
y_{CO2}=2,1644214686257133059e-12
y_{H2O}=0,0095647755410217215333
y_{CH4}=0,033227427279959260986
y_{NH3}=0,056489714129570559042
y_{AR}=0,0028103474906265852977
y_{O2}=0
y_{N2}=0,074621754644628474074
T: 573.15 °K
p: 180 bar
H: 926945.236802 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,405758327907986155e-07 kW (adiabat)
n_{CO}=4,6867916000030872059e-06 kmol/h
n_{H2}=165261,8177226120315 kmol/h
n_{CO2}=4,937499960393163275e-07 kmol/h
n_{H2O}=2284,6220429252957729 kmol/h
n_{CH4}=7936,6329588796561438 kmol/h
n_{NH3}=34417,366442606878991 kmol/h
n_{AR}=671,27365394022899636 kmol/h
n_{O2}=4,3182534299790744473e-19 kmol/h
n_{N2}=7361,8179501489867107 kmol/h
n_T=217933,53077629365725 kmol/h
y_{CO}=2,1505601195504085008e-11
y_{H2}=0,7583129458506843168
y_{CO2}=2,2655990304958863406e-12
y_{H2O}=0,01048311397877747797
y_{CH4}=0,036417677126639687313
y_{NH3}=0,15792598009131472714
y_{AR}=0,0030801761048385154808
y_{O2}=1,9814543519747375733e-24
y_{N2}=0,033780106823973823915
T: 721.143 °K
p: 180 bar
H: 1015943.607836 J/kmol
Gesamtfehler: 0.5061044578347682
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -949444,75532089534681 kW
Dampfphase (zum Splitter):
n_{CO}=4,6760171862919918198e-06 kmol/h
n_{H2}=165008,50078244769247 kmol/h
n_{CO2}=4,4483471139045104343e-07 kmol/h
n_{H2O}=38,93041677242310783 kmol/h
n_{CH4}=7863,0315724923739253 kmol/h
n_{NH3}=16989,207137540863187 kmol/h
n_{AR}=666,56539110510095725 kmol/h
n_{O2}=4,2867650475871553328e-19 kmol/h
n_{N2}=7346,1447232955106301 kmol/h
n_T=197912,38002877478721 kmol/h
y_{CO}=2,3626703825046373484e-11
y_{H2}=0,8337452197632658768
y_{CO2}=2,2476345912356276268e-12
y_{H2O}=0,00019670531356559098107
y_{CH4}=0,039729862130293974731
y_{NH3}=0,085842063719903688446
y_{AR}=0,0033679822909622215976
y_{O2}=2,1659913578550743121e-24
y_{N2}=0,037118166747129678618
H2/N2 Verhältnis: 22.46191805331385
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7084893.890067 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,0774413711095682201e-08 kmol/h
n_{H2}=253,31694016432354033 kmol/h
n_{CO2}=4,8915284648865257601e-08 kmol/h
n_{H2O}=2245,6916261528735959 kmol/h
n_{CH4}=73,601386387281422685 kmol/h
n_{NH3}=17428,159305065997614 kmol/h
n_{AR}=4,7082628351278401624 kmol/h
n_{O2}=3,1488382391919321447e-21 kmol/h
n_{N2}=15,673226853475188847 kmol/h
n_T=20021,150747518768185 kmol/h
x_{CO}=5,3815157020332511594e-13
x_{H2}=0,012652466553065873714
x_{CO2}=2,4431804779893208411e-12
x_{H2O}=0,11216596162091581335
x_{CH4}=0,0036761816202275018894
x_{NH3}=0,87048739237813987923
x_{AR}=0,00023516444658558971633
x_{O2}=1,5727558716186402543e-25
x_{N2}=0,00078283346709292610938
T: 294.15 °K
p: 180 bar
H: -67531046.798708 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,7408137490335933711e-06 kmol/h
n_{H2}=132006,8006259581598 kmol/h
n_{CO2}=3,5586776911236085592e-07 kmol/h
n_{H2O}=31,144333417938486974 kmol/h
n_{CH4}=6290,4252579938993222 kmol/h
n_{NH3}=13591,365710032690913 kmol/h
n_{AR}=533,2523128840807658 kmol/h
n_{O2}=3,4294120380697247477e-19 kmol/h
n_{N2}=5876,9157786364094136 kmol/h
n_T=158329,90402301988797 kmol/h
y_{CO}=2,362670382525912046e-11
y_{H2}=0,83374521977077331591
y_{CO2}=2,2476345912558664907e-12
y_{H2O}=0,00019670531356736218795
y_{CH4}=0,039729862130651723284
y_{NH3}=0,085842063720676653471
y_{AR}=0,0033679822909925484671
y_{O2}=2,1659913578745779674e-24
y_{N2}=0,037118166747463911259
T: 294.15 °K
p: 180 bar
H: -7084893.890067 J/kmol
========================================
Abgas:
n_{CO}=9,3520343725839813102e-07 kmol/h
n_{H2}=33001,700156489532674 kmol/h
n_{CO2}=8,896694227809018751e-08 kmol/h
n_{H2O}=7,7860833544846199672 kmol/h
n_{CH4}=1572,6063144984746032 kmol/h
n_{NH3}=3397,8414275081718188 kmol/h
n_{AR}=133,31307822102016303 kmol/h
n_{O2}=8,5735300951743094618e-20 kmol/h
n_{N2}=1469,2289446591016713 kmol/h
n_T=39582,476005754964717 kmol/h
y_{CO}=2,362670382525912046e-11
y_{H2}=0,83374521977077331591
y_{CO2}=2,2476345912558664907e-12
y_{H2O}=0,00019670531356736218795
y_{CH4}=0,039729862130651723284
y_{NH3}=0,085842063720676639593
y_{AR}=0,0033679822909925484671
y_{O2}=2,1659913578745779674e-24
y_{N2}=0,03711816674746390432
T: 294.15 °K
p: 180 bar
H: -7084893.890067 J/kmol
========================================
========================================
==============11. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 405.818 °K
Vorwärmer (auf T= 573.15 °K), Q: 341092,13239290780621 kW
n_{CO}=3,9306761958930722098e-06 kmol/h
n_{H2}=198479,10128874165821 kmol/h
n_{CO2}=4,8940464156634838573e-07 kmol/h
n_{H2O}=2284,9563119345657469 kmol/h
n_{CH4}=8075,6727041317044495 kmol/h
n_{NH3}=13644,436473916326577 kmol/h
n_{AR}=683,24969504617627081 kmol/h
n_{O2}=3,4294120380697242662e-19 kmol/h
n_{N2}=17548,0646468283594 kmol/h
n_T=240715,48112501885043 kmol/h
y_{CO}=1,632913752585618587e-11
y_{H2}=0,82453816580936400982
y_{CO2}=2,0331249127768786494e-12
y_{H2O}=0,0094923529689718722652
y_{CH4}=0,033548622076107745271
y_{NH3}=0,056682837390212979789
y_{AR}=0,0028384119370009328921
y_{O2}=1,4246744837689156657e-24
y_{N2}=0,072899609799980141789
T: 573.15 °K
p: 180 bar
H: 913021.967916 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 2,311452229817708297e-07 kW (adiabat)
n_{CO}=4,4056476884703235056e-06 kmol/h
n_{H2}=167099,69669218262425 kmol/h
n_{CO2}=4,6406765313935609257e-07 kmol/h
n_{H2O}=2284,9563115102682787 kmol/h
n_{CH4}=8075,6727036820702779 kmol/h
n_{NH3}=34564,039539171382785 kmol/h
n_{AR}=683,24969504617627081 kmol/h
n_{O2}=-8,4325084099167720438e-19 kmol/h
n_{N2}=7088,2631142008340248 kmol/h
n_T=219795,87806066308985 kmol/h
y_{CO}=2,0044268925072272441e-11
y_{H2}=0,76024945584313252667
y_{CO2}=2,1113573977546320767e-12
y_{H2O}=0,010395810566018104035
y_{CH4}=0,036741693133358968582
y_{NH3}=0,15725517623051965543
y_{AR}=0,0031085646422250065406
y_{O2}=-3,8365179931124193617e-24
y_{N2}=0,03224929956259003222
T: 719.908 °K
p: 180 bar
H: 999921.036848 J/kmol
Gesamtfehler: 0.8321386346126416
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -953811,89779997977894 kW
Dampfphase (zum Splitter):
n_{CO}=4,395616533017868629e-06 kmol/h
n_{H2}=166846,04416763101472 kmol/h
n_{CO2}=4,1847699018736354152e-07 kmol/h
n_{H2O}=39,277095712373409242 kmol/h
n_{CH4}=8001,4838439200666471 kmol/h
n_{NH3}=17140,7418526482179 kmol/h
n_{AR}=678,5028609389689791 kmol/h
n_{O2}=-8,3716018435247315051e-19 kmol/h
n_{N2}=7073,3169149937102702 kmol/h
n_T=199779,36674065844272 kmol/h
y_{CO}=2,2002354921288915435e-11
y_{H2}=0,83515153185323165452
y_{CO2}=2,0946957486697767689e-12
y_{H2O}=0,00019660236366154416887
y_{CH4}=0,040051602797575698578
y_{NH3}=0,085798359120564424152
y_{AR}=0,0033962609452739644759
y_{O2}=-4,1904236558707788787e-24
y_{N2}=0,035405642886596026819
H2/N2 Verhältnis: 23.588091156209618
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7106956.520890 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=1,0031155452455816235e-08 kmol/h
n_{H2}=253,65252455163283685 kmol/h
n_{CO2}=4,5590662951992590751e-08 kmol/h
n_{H2O}=2245,6792157978957221 kmol/h
n_{CH4}=74,188859762002792309 kmol/h
n_{NH3}=17423,297686523161246 kmol/h
n_{AR}=4,7468341072075199705 kmol/h
n_{O2}=-6,0906566392040087355e-21 kmol/h
n_{N2}=14,946199207124799102 kmol/h
n_T=20016,511320004647132 kmol/h
x_{CO}=5,0114404518291959827e-13
x_{H2}=0,012672164520543302557
x_{CO2}=2,277652795096414455e-12
x_{H2O}=0,11219133944461427699
x_{CH4}=0,0037063831245418704663
x_{NH3}=0,87044627355593062745
x_{AR}=0,00023714592576828643277
x_{O2}=-3,0428162742145946216e-25
x_{N2}=0,00074669351564425449647
T: 294.15 °K
p: 180 bar
H: -67537556.228914 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,5164932264142947338e-06 kmol/h
n_{H2}=133476,83533410480595 kmol/h
n_{CO2}=3,3478159214989088616e-07 kmol/h
n_{H2O}=31,421676569898728815 kmol/h
n_{CH4}=6401,1870751360538634 kmol/h
n_{NH3}=13712,593482118574684 kmol/h
n_{AR}=542,80228875117518328 kmol/h
n_{O2}=-6,6972814748197855892e-19 kmol/h
n_{N2}=5658,6535319949689438 kmol/h
n_T=159823,49339252678328 kmol/h
y_{CO}=2,2002354921486925026e-11
y_{H2}=0,83515153186074753133
y_{CO2}=2,0946957486886282474e-12
y_{H2O}=0,0001966023636633134784
y_{CH4}=0,040051602797936146361
y_{NH3}=0,085798359121336570388
y_{AR}=0,0033962609453045290026
y_{O2}=-4,1904236559084909415e-24
y_{N2}=0,035405642886914667766
T: 294.15 °K
p: 180 bar
H: -7106956.520890 J/kmol
========================================
Abgas:
n_{CO}=8,791233066035734717e-07 kmol/h
n_{H2}=33369,208833526194212 kmol/h
n_{CO2}=8,369539803747269507e-08 kmol/h
n_{H2O}=7,8554191424746804273 kmol/h
n_{CH4}=1600,2967687840130111 kmol/h
n_{NH3}=3428,1483705296427615 kmol/h
n_{AR}=135,7005721877937674 kmol/h
n_{O2}=-1,6743203687049459158e-19 kmol/h
n_{N2}=1414,6633829987417812 kmol/h
n_T=39955,873348131688545 kmol/h
y_{CO}=2,2002354921486925026e-11
y_{H2}=0,83515153186074753133
y_{CO2}=2,0946957486886278435e-12
y_{H2O}=0,0001966023636633134784
y_{CH4}=0,040051602797936139422
y_{NH3}=0,085798359121336570388
y_{AR}=0,0033962609453045290026
y_{O2}=-4,1904236559084902068e-24
y_{N2}=0,035405642886914660827
T: 294.15 °K
p: 180 bar
H: -7106956.520890 J/kmol
========================================
========================================
==============12. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 405.124 °K
Vorwärmer (auf T= 573.15 °K), Q: 344673,2386872349889 kW
n_{CO}=3,7063556732737735725e-06 kmol/h
n_{H2}=199949,13599688827526 kmol/h
n_{CO2}=4,6831846460387846891e-07 kmol/h
n_{H2O}=2285,2336550865256868 kmol/h
n_{CH4}=8186,4345212738599002 kmol/h
n_{NH3}=13765,664246002210348 kmol/h
n_{AR}=692,79967091327068829 kmol/h
n_{O2}=-6,6972814748197855892e-19 kmol/h
n_{N2}=17329,802400186923478 kmol/h
n_T=242209,07049452571664 kmol/h
y_{CO}=1,5302299231430075458e-11
y_{H2}=0,8255229070845528927
y_{CO2}=1,9335298370440801484e-12
y_{H2O}=0,0094349631515479315258
y_{CH4}=0,033799041896157580589
y_{NH3}=0,056833809806942525711
y_{AR}=0,002860337432858150921
y_{O2}=-2,7650828522423785301e-24
y_{N2}=0,071548940610705172305
T: 573.15 °K
p: 180 bar
H: 902371.061364 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,2751897176106772489e-07 kW (adiabat)
n_{CO}=4,1889673537791945963e-06 kmol/h
n_{H2}=168580,07216051142314 kmol/h
n_{CO2}=4,4126720598592136889e-07 kmol/h
n_{H2O}=2285,2336546580168033 kmol/h
n_{CH4}=8186,4345208182994611 kmol/h
n_{NH3}=34678,373471146529482 kmol/h
n_{AR}=692,79967091327068829 kmol/h
n_{O2}=-4,2289595193467221456e-19 kmol/h
n_{N2}=6873,4477876147630013 kmol/h
n_T=221296,36127029251656 kmol/h
y_{CO}=1,8929219304526963597e-11
y_{H2}=0,76178420283470849039
y_{CO2}=1,9940102198379814382e-12
y_{H2O}=0,010326575825920700918
y_{CH4}=0,036993082370746013798
y_{NH3}=0,15670557469668552897
y_{AR}=0,0031306419452016274498
y_{O2}=-1,9109936987086061622e-24
y_{N2}=0,031059922305814589155
T: 718.909 °K
p: 180 bar
H: 987645.954773 J/kmol
Gesamtfehler: 16.006584435190376
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -957259,95258935564198 kW
Dampfphase (zum Splitter):
n_{CO}=4,1795059947480392556e-06 kmol/h
n_{H2}=168326,24207922889036 kmol/h
n_{CO2}=3,9821778482171633358e-07 kmol/h
n_{H2O}=39,562192558769822881 kmol/h
n_{CH4}=8111,8173293609625034 kmol/h
n_{NH3}=17262,963737028032483 kmol/h
n_{AR}=688,02452533092832709 kmol/h
n_{O2}=-4,1986557136028691643e-19 kmol/h
n_{N2}=6859,0708432411820468 kmol/h
n_T=201287,68071132648038 kmol/h
y_{CO}=2,0763843966710220042e-11
y_{H2}=0,83624711399570605952
y_{CO2}=1,9783514987650040015e-12
y_{H2O}=0,00019654552339522661009
y_{CH4}=0,040299621420560004237
y_{NH3}=0,085762644171117077829
y_{AR}=0,0034181154201460809024
y_{O2}=-2,0858980036572951523e-24
y_{N2}=0,034075959437463901325
H2/N2 Verhältnis: 24.540676999289904
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7123876.205636 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=9,461359031155243039e-09 kmol/h
n_{H2}=253,83008128256253144 kmol/h
n_{CO2}=4,3049421164205035312e-08 kmol/h
n_{H2O}=2245,6714620992470373 kmol/h
n_{CH4}=74,617191457336218718 kmol/h
n_{NH3}=17415,409734118507913 kmol/h
n_{AR}=4,7751455823424224789 kmol/h
n_{O2}=-3,0303805743853018881e-21 kmol/h
n_{N2}=14,37694437357941446 kmol/h
n_T=20008,680558966079843 kmol/h
x_{CO}=4,7286271596553347535e-13
x_{H2}=0,012685997987581834959
x_{CO2}=2,1515372311121950177e-12
x_{H2O}=0,1122348600489460474
x_{CH4}=0,0037292409783891292477
x_{NH3}=0,87039271202060608523
x_{AR}=0,00023865369676406345857
x_{O2}=-1,5145329377042590079e-25
x_{N2}=0,00071853535431749425335
T: 294.15 °K
p: 180 bar
H: -67547331.429069 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,3436047957984316586e-06 kmol/h
n_{H2}=134660,99366338309483 kmol/h
n_{CO2}=3,1857422785737305628e-07 kmol/h
n_{H2O}=31,649754047015857594 kmol/h
n_{CH4}=6489,453863488771276 kmol/h
n_{NH3}=13810,37098962242635 kmol/h
n_{AR}=550,41962026474266167 kmol/h
n_{O2}=-3,3589245708822956203e-19 kmol/h
n_{N2}=5487,2566745929452736 kmol/h
n_T=161030,14456906117266 kmol/h
y_{CO}=2,0763843966894387282e-11
y_{H2}=0,8362471140031232375
y_{CO2}=1,9783514987825512972e-12
y_{H2O}=0,00019654552339696989877
y_{CH4}=0,040299621420917447479
y_{NH3}=0,085762644171877761012
y_{AR}=0,0034181154201763982309
y_{O2}=-2,0858980036757963313e-24
y_{N2}=0,034075959437766138727
T: 294.15 °K
p: 180 bar
H: -7123876.205636 J/kmol
========================================
Abgas:
n_{CO}=8,359011989496077029e-07 kmol/h
n_{H2}=33665,248415845766431 kmol/h
n_{CO2}=7,96435569643432376e-08 kmol/h
n_{H2O}=7,9124385117539626222 kmol/h
n_{CH4}=1622,3634658721923643 kmol/h
n_{NH3}=3452,5927474056056781 kmol/h
n_{AR}=137,604905066185637 kmol/h
n_{O2}=-8,3973114272057366434e-20 kmol/h
n_{N2}=1371,814168648236091 kmol/h
n_T=40257,536142265285889 kmol/h
y_{CO}=2,0763843966894384051e-11
y_{H2}=0,83624711400312312648
y_{CO2}=1,9783514987825508933e-12
y_{H2O}=0,00019654552339696989877
y_{CH4}=0,040299621420917447479
y_{NH3}=0,085762644171877761012
y_{AR}=0,0034181154201763982309
y_{O2}=-2,0858980036757963313e-24
y_{N2}=0,034075959437766138727
T: 294.15 °K
p: 180 bar
H: -7123876.205636 J/kmol
========================================
========================================
==============13. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 404.57 °K
Vorwärmer (auf T= 573.15 °K), Q: 347565,11902262433432 kW
n_{CO}=3,5334672426579104973e-06 kmol/h
n_{H2}=201133,29432616656413 kmol/h
n_{CO2}=4,5211110031136069197e-07 kmol/h
n_{H2O}=2285,4617325636427267 kmol/h
n_{CH4}=8274,7013096265764034 kmol/h
n_{NH3}=13863,441753506062014 kmol/h
n_{AR}=700,41700242683816668 kmol/h
n_{O2}=-3,3589245708822956203e-19 kmol/h
n_{N2}=17158,405542784897989 kmol/h
n_T=243415,72167106013512 kmol/h
y_{CO}=1,4516183336065949483e-11
y_{H2}=0,82629541323533761688
y_{CO2}=1,8573619534826965356e-12
y_{H2O}=0,0093891294977737783239
y_{CH4}=0,033994112018814442999
y_{NH3}=0,056953764770545207974
y_{AR}=0,0028774517833870514628
y_{O2}=-1,3799127467293910928e-24
y_{N2}=0,070490128677768451593
T: 573.15 °K
p: 180 bar
H: 894243.917356 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 3,5442776150173611062e-08 kW (adiabat)
n_{CO}=4,0214383738623027449e-06 kmol/h
n_{H2}=169774,02918620113633 kmol/h
n_{CO2}=4,2366405267855111046e-07 kmol/h
n_{H2O}=2285,461732132565885 kmol/h
n_{CH4}=8274,7013091670523863 kmol/h
n_{NH3}=34769,618514383109869 kmol/h
n_{AR}=700,41700242683816668 kmol/h
n_{O2}=-3,610601326033017555e-18 kmol/h
n_{N2}=6705,3171623463776996 kmol/h
n_T=222509,54491110218805 kmol/h
y_{CO}=1,807310502328770733e-11
y_{H2}=0,7629966132645225052
y_{CO2}=1,9040264220926563118e-12
y_{H2O}=0,010271297498925998151
y_{CH4}=0,037188073493534812286
y_{NH3}=0,15626124500984617249
y_{AR}=0,0031478065478344817267
y_{O2}=-1,6226725588223814306e-23
y_{N2}=0,030134964165358886501
T: 718.104 °K
p: 180 bar
H: 978263.780011 J/kmol
Gesamtfehler: 197928.00509823597
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -960024,55007687932812 kW
Dampfphase (zum Splitter):
n_{CO}=4,0124150411649144989e-06 kmol/h
n_{H2}=169520,09268558592885 kmol/h
n_{CO2}=3,8256688037646244533e-07 kmol/h
n_{H2O}=39,794926181034988133 kmol/h
n_{CH4}=8199,7634471292803937 kmol/h
n_{NH3}=17361,898658289355808 kmol/h
n_{AR}=695,62055486696829121 kmol/h
n_{O2}=-3,5848956465704239522e-18 kmol/h
n_{N2}=6691,3840894746899721 kmol/h
n_T=202508,55436592220212 kmol/h
y_{CO}=1,9813558265191670802e-11
y_{H2}=0,83710089786010721813
y_{CO2}=1,8891393579441284964e-12
y_{H2O}=0,00019650985265921565195
y_{CH4}=0,040490948506991045197
y_{NH3}=0,085734149416531013621
y_{AR}=0,0034350181257221420843
y_{O2}=-1,7702440559921043899e-23
y_{N2}=0,033042476207319676496
H2/N2 Verhältnis: 25.334084909613097
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7136887.031260 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=9,0233326973876818749e-09 kmol/h
n_{H2}=253,93650061519855399 kmol/h
n_{CO2}=4,1097172302088671749e-08 kmol/h
n_{H2O}=2245,6668059515309324 kmol/h
n_{CH4}=74,937862037771594714 kmol/h
n_{NH3}=17407,719856093750423 kmol/h
n_{AR}=4,7964475598698586012 kmol/h
n_{O2}=-2,5705679462594376194e-20 kmol/h
n_{N2}=13,933072871687254946 kmol/h
n_T=20000,99054517993136 kmol/h
x_{CO}=4,5114429097020168214e-13
x_{H2}=0,012696196224114005002
x_{CO2}=2,0547568488163669659e-12
x_{H2O}=0,11227777949710601724
x_{CH4}=0,0037467075380741366245
x_{NH3}=0,87034288718611996227
x_{AR}=0,00023981050085848017455
x_{O2}=-1,2852203198067626606e-24
x_{N2}=0,00069661914201094336189
T: 294.15 °K
p: 180 bar
H: -67556729.210431 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,2099320329319320227e-06 kmol/h
n_{H2}=135616,07414846873144 kmol/h
n_{CO2}=3,0605350430116999862e-07 kmol/h
n_{H2O}=31,835940944827992638 kmol/h
n_{CH4}=6559,8107577034252245 kmol/h
n_{NH3}=13889,518926631484646 kmol/h
n_{AR}=556,49644389357467844 kmol/h
n_{O2}=-2,8679165172563392388e-18 kmol/h
n_{N2}=5353,1072715797527053 kmol/h
n_T=162006,84349273773842 kmol/h
y_{CO}=1,9813558265369346613e-11
y_{H2}=0,83710089786761365804
y_{CO2}=1,8891393579610691392e-12
y_{H2O}=0,00019650985266097785995
y_{CH4}=0,040490948507354143637
y_{NH3}=0,08573414941729981531
y_{AR}=0,0034350181257529447017
y_{O2}=-1,7702440560079788534e-23
y_{N2}=0,033042476207615981143
T: 294.15 °K
p: 180 bar
H: -7136887.031260 J/kmol
========================================
Abgas:
n_{CO}=8,024830082329827939e-07 kmol/h
n_{H2}=33904,018537117175583 kmol/h
n_{CO2}=7,6513376075292486419e-08 kmol/h
n_{H2O}=7,958985236206995495 kmol/h
n_{CH4}=1639,9526894258558514 kmol/h
n_{NH3}=3472,3797316578702521 kmol/h
n_{AR}=139,12411097339364119 kmol/h
n_{O2}=-7,1697912931408461711e-19 kmol/h
n_{N2}=1338,2768178949377216 kmol/h
n_T=40501,710873184427328 kmol/h
y_{CO}=1,9813558265369343382e-11
y_{H2}=0,83710089786761365804
y_{CO2}=1,8891393579610691392e-12
y_{H2O}=0,00019650985266097780574
y_{CH4}=0,040490948507354136698
y_{NH3}=0,08573414941729981531
y_{AR}=0,0034350181257529447017
y_{O2}=-1,7702440560079788534e-23
y_{N2}=0,033042476207615974204
T: 294.15 °K
p: 180 bar
H: -7136887.031260 J/kmol
========================================
========================================
==============14. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 404.126 °K
Vorwärmer (auf T= 573.15 °K), Q: 349904,90117685322184 kW
n_{CO}=3,3997944797914108613e-06 kmol/h
n_{H2}=202088,37481125220074 kmol/h
n_{CO2}=4,3959037675515758137e-07 kmol/h
n_{H2O}=2285,6479194614553307 kmol/h
n_{CH4}=8345,0582038412303518 kmol/h
n_{NH3}=13942,58969051512031 kmol/h
n_{AR}=706,49382605567018345 kmol/h
n_{O2}=-2,8679165172563392388e-18 kmol/h
n_{N2}=17024,25613977170724 kmol/h
n_T=244392,42059473678819 kmol/h
y_{CO}=1,3911210795809060053e-11
y_{H2}=0,82690115478812176164
y_{CO2}=1,7987070780894117923e-12
y_{H2O}=0,0093523682686200235864
y_{CH4}=0,034146141617376120359
y_{NH3}=0,057050008574674210271
y_{AR}=0,0028908172534008822613
y_{O2}=-1,1734883227054146473e-23
y_{N2}=0,069659509482097009547
T: 573.15 °K
p: 180 bar
H: 888041.121354 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -1,1681450737847222348e-08 kW (adiabat)
n_{CO}=3,8914328152097463743e-06 kmol/h
n_{H2}=170737,07501900388161 kmol/h
n_{CO2}=4,1000808073188196812e-07 kmol/h
n_{H2O}=2285,6479190289815051 kmol/h
n_{CH4}=8345,0582033791743015 kmol/h
n_{NH3}=34843,456219585073995 kmol/h
n_{AR}=706,49382605567018345 kmol/h
n_{O2}=-2,3444595004723260923e-18 kmol/h
n_{N2}=6573,8228752367294874 kmol/h
n_T=223491,55406659096479 kmol/h
y_{CO}=1,7411990495400400702e-11
y_{H2}=0,76395314235513123169
y_{CO2}=1,8345573838093094503e-12
y_{H2O}=0,010226999085379108803
y_{CH4}=0,03733947906099709807
y_{NH3}=0,15590502453261928517
y_{AR}=0,0031611656601804516073
y_{O2}=-1,0490148096485905269e-23
y_{N2}=0,029414189286446189991
T: 717.459 °K
p: 180 bar
H: 971090.474277 J/kmol
Gesamtfehler: 486552.0006133561
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -962260,39377604692709 kW
Dampfphase (zum Splitter):
n_{CO}=3,8827475163677572465e-06 kmol/h
n_{H2}=170483,06267257520813 kmol/h
n_{CO2}=3,7041836093940727435e-07 kmol/h
n_{H2O}=39,983823444532745839 kmol/h
n_{CH4}=8269,8750093039070634 kmol/h
n_{NH3}=17442,071526155974425 kmol/h
n_{AR}=701,68102375299918094 kmol/h
n_{O2}=-2,3278552062648315399e-18 kmol/h
n_{N2}=6560,2355925291349195 kmol/h
n_T=203496,90965201490326 kmol/h
y_{CO}=1,9080130125674643616e-11
y_{H2}=0,83776733004242698311
y_{CO2}=1,8202652883993480654e-12
y_{H2O}=0,00019648368868377047501
y_{CH4}=0,040638823574135833627
y_{NH3}=0,085711726806204049933
y_{AR}=0,0034481163617994456394
y_{O2}=-1,1439265639093721886e-23
y_{N2}=0,032237519496923841555
H2/N2 Verhältnis: 25.987338452710922
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7146924.969283 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=8,6852988419888250734e-09 kmol/h
n_{H2}=254,01234642867152047 kmol/h
n_{CO2}=3,9589719792474693765e-08 kmol/h
n_{H2O}=2245,6640955844504788 kmol/h
n_{CH4}=75,183194075264978551 kmol/h
n_{NH3}=17401,384693429088657 kmol/h
n_{AR}=4,8128023026709563226 kmol/h
n_{O2}=-1,6604294207494269573e-20 kmol/h
n_{N2}=13,587282707594487974 kmol/h
n_T=19994,64441457601788 kmol/h
x_{CO}=4,3438126043623252094e-13
x_{H2}=0,01270401919558880946
x_{CO2}=1,9800161970977747278e-12
x_{H2O}=0,11231327995767549643
x_{CH4}=0,0037601665987761429336
x_{NH3}=0,87030228366173445487
x_{AR}=0,00024070457084996436286
x_{O2}=-8,3043708428733836473e-25
x_{N2}=0,00067954610380186093472
T: 294.15 °K
p: 180 bar
H: -67564456.466454 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,1061980130942060513e-06 kmol/h
n_{H2}=136386,45013806017232 kmol/h
n_{CO2}=2,9633468875152587242e-07 kmol/h
n_{H2O}=31,987058755626200934 kmol/h
n_{CH4}=6615,9000074431260146 kmol/h
n_{NH3}=13953,657220924780631 kmol/h
n_{AR}=561,34481900239939023 kmol/h
n_{O2}=-1,8622841650118651549e-18 kmol/h
n_{N2}=5248,188474023309027 kmol/h
n_T=162797,52772161195753 kmol/h
y_{CO}=1,9080130125844945887e-11
y_{H2}=0,83776733004990466824
y_{CO2}=1,8202652884155952174e-12
y_{H2O}=0,00019648368868552422623
y_{CH4}=0,040638823574498557367
y_{NH3}=0,085711726806969090742
y_{AR}=0,003448116361830222236
y_{O2}=-1,1439265639195823856e-23
y_{N2}=0,032237519497211583608
T: 294.15 °K
p: 180 bar
H: -7146924.969283 J/kmol
========================================
Abgas:
n_{CO}=7,7654950327355130107e-07 kmol/h
n_{H2}=34096,612534515028528 kmol/h
n_{CO2}=7,4083672187881441635e-08 kmol/h
n_{H2O}=7,996764688906547569 kmol/h
n_{CH4}=1653,9750018607810489 kmol/h
n_{NH3}=3488,4143052311937936 kmol/h
n_{AR}=140,33620475059981914 kmol/h
n_{O2}=-4,6557104125296619242e-19 kmol/h
n_{N2}=1312,0471185058265746 kmol/h
n_T=40699,381930402974831 kmol/h
y_{CO}=1,9080130125844949118e-11
y_{H2}=0,83776733004990466824
y_{CO2}=1,8202652884155952174e-12
y_{H2O}=0,00019648368868552422623
y_{CH4}=0,040638823574498564306
y_{NH3}=0,085711726806969090742
y_{AR}=0,0034481163618302226696
y_{O2}=-1,1439265639195826795e-23
y_{N2}=0,032237519497211583608
T: 294.15 °K
p: 180 bar
H: -7146924.969283 J/kmol
========================================
========================================
==============15. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 403.769 °K
Vorwärmer (auf T= 573.15 °K), Q: 351798,32765445054974 kW
n_{CO}=3,29606045995368489e-06 kmol/h
n_{H2}=202858,75080084364163 kmol/h
n_{CO2}=4,2987156120551340223e-07 kmol/h
n_{H2O}=2285,7990372722529173 kmol/h
n_{CH4}=8401,1474535809320514 kmol/h
n_{NH3}=14006,727984808414476 kmol/h
n_{AR}=711,34220116449489524 kmol/h
n_{O2}=-1,8622841650118651549e-18 kmol/h
n_{N2}=16919,337342215261742 kmol/h
n_T=245183,10482361091999 kmol/h
y_{CO}=1,3443260955215202061e-11
y_{H2}=0,82737654760830214862
y_{CO2}=1,7532674672456351484e-12
y_{H2O}=0,0093228244210248386453
y_{CH4}=0,034264789409632720463
y_{NH3}=0,05712762302641163914
y_{AR}=0,0029012692439646160271
y_{O2}=-7,595483246497043957e-24
y_{N2}=0,069006946275467606622
T: 573.15 °K
p: 180 bar
H: 883297.726400 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 2,1983888414171008459e-07 kW (adiabat)
n_{CO}=3,7901569247595574839e-06 kmol/h
n_{H2}=171513,42152424855158 kmol/h
n_{CO2}=3,9936674143623614784e-07 kmol/h
n_{H2O}=2285,7990368391660922 kmol/h
n_{CH4}=8401,147453117340774 kmol/h
n_{NH3}=34903,614170112014108 kmol/h
n_{AR}=711,34220116449489524 kmol/h
n_{O2}=4,5973652571093378425e-19 kmol/h
n_{N2}=6470,8942495634628358 kmol/h
n_T=224286,21863923454657 kmol/h
y_{CO}=1,6898750836118215125e-11
y_{H2}=0,76470780311352393177
y_{CO2}=1,7806120405401254223e-12
y_{H2O}=0,010191437756217580982
y_{CH4}=0,037457261101854086305
y_{NH3}=0,15562085972948094814
y_{AR}=0,003171582299974891328
y_{O2}=2,0497760785312545928e-24
y_{N2}=0,0288510559802692447
T: 716.944 °K
p: 180 bar
H: 965595.123754 J/kmol
Gesamtfehler: 32.00978460276329
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -964075,70391753234435 kW
Dampfphase (zum Splitter):
n_{CO}=3,781733623373493073e-06 kmol/h
n_{H2}=171259,34667662280845 kmol/h
n_{CO2}=3,6094678787923185025e-07 kmol/h
n_{H2O}=40,136478575268377256 kmol/h
n_{CH4}=8325,7735210986356833 kmol/h
n_{NH3}=17507,01529579423368 kmol/h
n_{AR}=706,51665315235140952 kmol/h
n_{O2}=4,5649412809181370347e-19 kmol/h
n_{N2}=6457,5766255545868262 kmol/h
n_T=204296,3652549405524 kmol/h
y_{CO}=1,8511017650848209373e-11
y_{H2}=0,83828875984547424061
y_{CO2}=1,766780272453247035e-12
y_{H2O}=0,00019646202967805027721
y_{CH4}=0,040753409931749799699
y_{NH3}=0,085694208378703257134
y_{AR}=0,0034582928200677580215
y_{O2}=2,2344701409926796697e-24
y_{N2}=0,031608866938310019312
H2/N2 Verhältnis: 26.52068362594378
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7154696.296584 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=8,4233013860634597141e-09 kmol/h
n_{H2}=254,07484762572977388 kmol/h
n_{CO2}=3,8419953557004204948e-08 kmol/h
n_{H2O}=2245,6625582638998821 kmol/h
n_{CH4}=75,373932018706383928 kmol/h
n_{NH3}=17396,598874317798618 kmol/h
n_{AR}=4,8255480121434697338 kmol/h
n_{O2}=3,2423976191200093122e-21 kmol/h
n_{N2}=13,317624008875986519 kmol/h
n_T=19989,853384293997806 kmol/h
x_{CO}=4,213788479188291393e-13
x_{H2}=0,012710190656933892384
x_{CO2}=1,9219727544987297135e-12
x_{H2O}=0,11234012155629682916
x_{CH4}=0,0037706095486152138747
x_{NH3}=0,8702714595365907968
x_{AR}=0,00024139987028106230029
x_{O2}=1,6220217117009267963e-25
x_{N2}=0,00066621919419398826796
T: 294.15 °K
p: 180 bar
H: -67570313.227222 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=3,0253868986987949666e-06 kmol/h
n_{H2}=137007,47734129824676 kmol/h
n_{CO2}=2,8875743030338549079e-07 kmol/h
n_{H2O}=32,109182860214701805 kmol/h
n_{CH4}=6660,6188168789085466 kmol/h
n_{NH3}=14005,61223663538658 kmol/h
n_{AR}=565,21332252188108214 kmol/h
n_{O2}=3,6519530247345099166e-19 kmol/h
n_{N2}=5166,0613004436700066 kmol/h
n_T=163437,09220395248849 kmol/h
y_{CO}=1,8511017651509772917e-11
y_{H2}=0,83828875987543371995
y_{CO2}=1,7667802725163896328e-12
y_{H2O}=0,00019646202968507159759
y_{CH4}=0,040753409933206280469
y_{NH3}=0,085694208381765876736
y_{AR}=0,003458292820191353166
y_{O2}=2,2344701410725372458e-24
y_{N2}=0,031608866939439685118
T: 294.15 °K
p: 180 bar
H: -7154696.296584 J/kmol
========================================
Abgas:
n_{CO}=7,5634672467469842401e-07 kmol/h
n_{H2}=34251,869335324554413 kmol/h
n_{CO2}=7,2189357575846359462e-08 kmol/h
n_{H2O}=8,0272957150536736748 kmol/h
n_{CH4}=1665,1547042197266819 kmol/h
n_{NH3}=3501,4030591588457355 kmol/h
n_{AR}=141,30333063047024211 kmol/h
n_{O2}=9,1298825618362723842e-20 kmol/h
n_{N2}=1291,5153251109170469 kmol/h
n_T=40859,273050988114846 kmol/h
y_{CO}=1,8511017651509769686e-11
y_{H2}=0,83828875987543371995
y_{CO2}=1,7667802725163896328e-12
y_{H2O}=0,00019646202968507159759
y_{CH4}=0,040753409933206280469
y_{NH3}=0,085694208381765862859
y_{AR}=0,003458292820191353166
y_{O2}=2,2344701410725368785e-24
y_{N2}=0,031608866939439685118
T: 294.15 °K
p: 180 bar
H: -7154696.296584 J/kmol
========================================
========================================
==============16. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 403.482 °K
Vorwärmer (auf T= 573.15 °K), Q: 353329,34111563005717 kW
n_{CO}=3,2152493455582742288e-06 kmol/h
n_{H2}=203479,77800408171606 kmol/h
n_{CO2}=4,2229430275737307354e-07 kmol/h
n_{H2O}=2285,92116137684161 kmol/h
n_{CH4}=8445,8662630167145835 kmol/h
n_{NH3}=14058,683000519022244 kmol/h
n_{AR}=715,21070468397658715 kmol/h
n_{O2}=3,6519530247345099166e-19 kmol/h
n_{N2}=16837,21016863562545 kmol/h
n_T=245822,66930595148006 kmol/h
y_{CO}=1,307954776764939991e-11
y_{H2}=0,82775025825966563886
y_{CO2}=1,7178818534094777384e-12
y_{H2O}=0,009299065736414159275
y_{CH4}=0,034357556554334575671
y_{NH3}=0,057190343918288318037
y_{AR}=0,002909457889718965011
y_{O2}=1,4856046576360622131e-24
y_{N2}=0,068493317626780764185
T: 573.15 °K
p: 180 bar
H: 879659.657136 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -4,3449401855468753121e-08 kW (adiabat)
n_{CO}=3,7109652633843814455e-06 kmol/h
n_{H2}=172138,70189019705867 kmol/h
n_{CO2}=3,9104076172225228267e-07 kmol/h
n_{H2O}=2285,9211609436329127 kmol/h
n_{CH4}=8445,8662625522520102 kmol/h
n_{NH3}=34952,733744016884884 kmol/h
n_{AR}=715,21070468397658715 kmol/h
n_{O2}=-1,0835600487931166259e-18 kmol/h
n_{N2}=6390,1847968866959491 kmol/h
n_T=224928,618563382508 kmol/h
y_{CO}=1,6498413083609771134e-11
y_{H2}=0,76530369052033364596
y_{CO2}=1,7385104848810562221e-12
y_{H2O}=0,010162873784331203503
y_{CH4}=0,037549095870929811991
y_{NH3}=0,15539478243035390048
y_{AR}=0,0031797230128030053685
y_{O2}=-4,8173507476007584376e-24
y_{N2}=0,028409834363011522013
T: 716.532 °K
p: 180 bar
H: 961372.929682 J/kmol
Gesamtfehler: 24.000509833549668
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -965550,9740772616351 kW
Dampfphase (zum Splitter):
n_{CO}=3,7027459103350727072e-06 kmol/h
n_{H2}=171884,57154548866674 kmol/h
n_{CO2}=3,5353271346431567948e-07 kmol/h
n_{H2O}=40,259453805872155385 kmol/h
n_{CH4}=8370,3424003645141056 kmol/h
n_{NH3}=17559,561349268729828 kmol/h
n_{AR}=710,37512132732445025 kmol/h
n_{O2}=-1,0759435055152317885e-18 kmol/h
n_{N2}=6377,077902127809466 kmol/h
n_T=204942,18777643918293 kmol/h
y_{CO}=1,8067270337905619211e-11
y_{H2}=0,83869784647102585406
y_{CO2}=1,7250363006612854343e-12
y_{H2O}=0,00019644297858431575407
y_{CH4}=0,040842456552611337839
y_{NH3}=0,085680559669720268712
y_{AR}=0,0034662220063546942544
y_{O2}=-5,2499854576028440436e-24
y_{N2}=0,03111647226509282535
H2/N2 Verhältnis: 26.9535003623112
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7160733.356603 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=8,2193530493090873582e-09 kmol/h
n_{H2}=254,13034470836564083 kmol/h
n_{CO2}=3,7508048257936523775e-08 kmol/h
n_{H2O}=2245,6617071377590946 kmol/h
n_{CH4}=75,523862187738416196 kmol/h
n_{NH3}=17393,172394748136867 kmol/h
n_{AR}=4,8355833566522443689 kmol/h
n_{O2}=-7,6165432778848750357e-21 kmol/h
n_{N2}=13,106894758885198726 kmol/h
n_T=19986,430786943263229 kmol/h
x_{CO}=4,1124666730298503014e-13
x_{H2}=0,012715143965090927244
x_{CO2}=1,876675664201156259e-12
x_{H2O}=0,11235931677469020162
x_{CH4}=0,0037787568486510191186
x_{NH3}=0,87024904980419559575
x_{AR}=0,00024194331694465647116
x_{O2}=-3,8108571570148154815e-25
x_{N2}=0,0006557896656763749629
T: 294.15 °K
p: 180 bar
H: -67574535.608773 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,9621967282680585893e-06 kmol/h
n_{H2}=137507,65723639092175 kmol/h
n_{CO2}=2,8282617077145254359e-07 kmol/h
n_{H2O}=32,207563044697721466 kmol/h
n_{CH4}=6696,2739202916118302 kmol/h
n_{NH3}=14047,649079414986772 kmol/h
n_{AR}=568,3000970618595602 kmol/h
n_{O2}=-8,6075480441218535375e-19 kmol/h
n_{N2}=5101,6623217022488461 kmol/h
n_T=163953,7502211513638 kmol/h
y_{CO}=1,8067270338570830751e-11
y_{H2}=0,8386978465019052642
y_{CO2}=1,7250363007247986074e-12
y_{H2O}=0,00019644297859154849386
y_{CH4}=0,040842456554115093292
y_{NH3}=0,085680559672874911925
y_{AR}=0,0034662220064823152585
y_{O2}=-5,2499854577961408652e-24
y_{N2}=0,031116472266238488775
T: 294.15 °K
p: 180 bar
H: -7160733.356603 J/kmol
========================================
Abgas:
n_{CO}=7,4054918206701443556e-07 kmol/h
n_{H2}=34376,914309097723162 kmol/h
n_{CO2}=7,0706542692863109427e-08 kmol/h
n_{H2O}=8,0518907611744285902 kmol/h
n_{CH4}=1674,0684800729025028 kmol/h
n_{NH3}=3511,9122698537457836 kmol/h
n_{AR}=142,07502426546486163 kmol/h
n_{O2}=-2,1518870110304629029e-19 kmol/h
n_{N2}=1275,4155804255615294 kmol/h
n_T=40988,437555287833675 kmol/h
y_{CO}=1,806727033857082752e-11
y_{H2}=0,8386978465019052642
y_{CO2}=1,7250363007247982035e-12
y_{H2O}=0,00019644297859154846676
y_{CH4}=0,040842456554115086353
y_{NH3}=0,085680559672874898047
y_{AR}=0,0034662220064823152585
y_{O2}=-5,2499854577961401306e-24
y_{N2}=0,031116472266238481836
T: 294.15 °K
p: 180 bar
H: -7160733.356603 J/kmol
========================================
========================================
==============17. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 403.251 °K
Vorwärmer (auf T= 573.15 °K), Q: 354565,76147810852854 kW
n_{CO}=3,1520591751275370045e-06 kmol/h
n_{H2}=203979,95789917439106 kmol/h
n_{CO2}=4,1636304322544012633e-07 kmol/h
n_{H2O}=2286,019541561324786 kmol/h
n_{CH4}=8481,5213664294187765 kmol/h
n_{NH3}=14100,719843298620617 kmol/h
n_{AR}=718,29747922395506521 kmol/h
n_{O2}=-8,6075480441218535375e-19 kmol/h
n_{N2}=16772,81118989420429 kmol/h
n_T=246339,32732315035537 kmol/h
y_{CO}=1,2795598694611334505e-11
y_{H2}=0,82804463305037556697
y_{CO2}=1,6902012672919699043e-12
y_{H2O}=0,0092799617763123197489
y_{CH4}=0,034430236773778613579
y_{NH3}=0,057241042250639737055
y_{AR}=0,0029158863386912043346
y_{O2}=-3,4941834654076110671e-24
y_{N2}=0,068088239795716681835
T: 573.15 °K
p: 180 bar
H: 876859.861627 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,4509624905056423499e-07 kW (adiabat)
n_{CO}=3,6488260830218195381e-06 kmol/h
n_{H2}=172641,80605929280864 kmol/h
n_{CO2}=3,845027980951171087e-07 kmol/h
n_{H2O}=2286,0195411282784335 kmol/h
n_{CH4}=8481,5213659645105508 kmol/h
n_{NH3}=34992,821070794896514 kmol/h
n_{AR}=718,29747922395506521 kmol/h
n_{O2}=4,2222759643263669419e-19 kmol/h
n_{N2}=6326,7605761460645226 kmol/h
n_T=225447,22609658385045 kmol/h
y_{CO}=1,6184834678154904908e-11
y_{H2}=0,76577480702881373098
y_{CO2}=1,705511328537669754e-12
y_{H2O}=0,010139931995210819601
y_{CH4}=0,037620872577651245927
y_{NH3}=0,15521513250202342848
y_{AR}=0,0031861003200643915265
y_{O2}=1,8728444955528090543e-24
y_{N2}=0,028063155558346132568
T: 716.204 °K
p: 180 bar
H: 958118.102451 J/kmol
Gesamtfehler: 40.003409742501084
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -966749,0230725936126 kW
Dampfphase (zum Splitter):
n_{CO}=3,6407661427937780179e-06 kmol/h
n_{H2}=172387,62544919201173 kmol/h
n_{CO2}=3,4770858205055899892e-07 kmol/h
n_{H2O}=40,35829288597089004 kmol/h
n_{CH4}=8405,8788292657973216 kmol/h
n_{NH3}=17602,012629652559554 kmol/h
n_{AR}=713,4539427508685776 kmol/h
n_{O2}=4,1926757032885486064e-19 kmol/h
n_{N2}=6313,8187847239323673 kmol/h
n_T=205463,14793245962937 kmol/h
y_{CO}=1,7719801235856676457e-11
y_{H2}=0,83901968395502490861
y_{CO2}=1,6923160456577728735e-12
y_{H2O}=0,00019642594446044872245
y_{CH4}=0,04091185652286551816
y_{NH3}=0,085669925756104603476
y_{AR}=0,0034724180462693756029
y_{O2}=2,0405974235870291003e-24
y_{N2}=0,030729689718185061037
H2/N2 Verhältnis: 27.30322667262449
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7165438.066737 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=8,0599402280421736856e-09 kmol/h
n_{H2}=254,18061010083670226 kmol/h
n_{CO2}=3,6794216044558142867e-08 kmol/h
n_{H2O}=2245,6612482423056463 kmol/h
n_{CH4}=75,642536698715403531 kmol/h
n_{NH3}=17390,80844114233696 kmol/h
n_{AR}=4,8435364730865000382 kmol/h
n_{O2}=2,9600261037817729884e-21 kmol/h
n_{N2}=12,94179142213140743 kmol/h
n_T=19984,078164124268369 kmol/h
x_{CO}=4,0331808977978166046e-13
x_{H2}=0,012719156125780702385
x_{CO2}=1,8411765484817358997e-12
x_{H2O}=0,11237252129766384101
x_{CH4}=0,0037851401554169555527
x_{NH3}=0,87023320790945790648
x_{AR}=0,00024236977233495760856
x_{O2}=1,4811922174335355129e-25
x_{N2}=0,00064760512448245547562
T: 294.15 °K
p: 180 bar
H: -67577478.952739 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,9126129142350223296e-06 kmol/h
n_{H2}=137910,10035935364431 kmol/h
n_{CO2}=2,7816686564044724149e-07 kmol/h
n_{H2O}=32,286634308776719138 kmol/h
n_{CH4}=6724,7030634126385849 kmol/h
n_{NH3}=14081,610103722048734 kmol/h
n_{AR}=570,76315420069488482 kmol/h
n_{O2}=3,3541405626308390777e-19 kmol/h
n_{N2}=5051,0550277791462577 kmol/h
n_T=164370,51834596772096 kmol/h
y_{CO}=1,7719801236524324303e-11
y_{H2}=0,83901968398663751003
y_{CO2}=1,6923160457215358568e-12
y_{H2O}=0,0001964259444678496491
y_{CH4}=0,040911856524406993441
y_{NH3}=0,085669925759332465898
y_{AR}=0,0034724180464002088811
y_{O2}=2,0405974236639145124e-24
y_{N2}=0,030729689719342891813
T: 294.15 °K
p: 180 bar
H: -7165438.066737 J/kmol
========================================
Abgas:
n_{CO}=7,2815322855875537064e-07 kmol/h
n_{H2}=34477,525089838396525 kmol/h
n_{CO2}=6,9541716410111797137e-08 kmol/h
n_{H2O}=8,0716585771941762317 kmol/h
n_{CH4}=1681,1757658531591915 kmol/h
n_{NH3}=3520,4025259305112741 kmol/h
n_{AR}=142,69078855017369278 kmol/h
n_{O2}=8,3853514065770952869e-20 kmol/h
n_{N2}=1262,7637569447861097 kmol/h
n_T=41092,629586491915688 kmol/h
y_{CO}=1,7719801236524324303e-11
y_{H2}=0,83901968398663739901
y_{CO2}=1,6923160457215360587e-12
y_{H2O}=0,0001964259444678496491
y_{CH4}=0,040911856524406993441
y_{NH3}=0,085669925759332479775
y_{AR}=0,0034724180464002093148
y_{O2}=2,0405974236639148797e-24
y_{N2}=0,030729689719342891813
T: 294.15 °K
p: 180 bar
H: -7165438.066737 J/kmol
========================================
========================================
==============18. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 403.066 °K
Vorwärmer (auf T= 573.15 °K), Q: 355562,87200810742797 kW
n_{CO}=3,1024753610945011683e-06 kmol/h
n_{H2}=204382,40102213711361 kmol/h
n_{CO2}=4,1170373809443482424e-07 kmol/h
n_{H2O}=2286,0986128254039613 kmol/h
n_{CH4}=8509,9505095504446217 kmol/h
n_{NH3}=14134,680867605684398 kmol/h
n_{AR}=720,76053636279038983 kmol/h
n_{O2}=3,3541405626308390777e-19 kmol/h
n_{N2}=16722,203895971098973 kmol/h
n_T=246756,09544796668342 kmol/h
y_{CO}=1,2573044469123227957e-11
y_{H2}=0,82827701034536382885
y_{CO2}=1,6684643082352976928e-12
y_{H2O}=0,0092646084737042378593
y_{CH4}=0,034487296024445862619
y_{NH3}=0,057281992738397236042
y_{AR}=0,002920943189080314837
y_{O2}=1,3592939037804335513e-24
y_{N2}=0,067768149214767023358
T: 573.15 °K
p: 180 bar
H: 874697.684486 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 6,5066019694010421341e-08 kW (adiabat)
n_{CO}=3,5999149427434647797e-06 kmol/h
n_{H2}=173046,20670295078889 kmol/h
n_{CO2}=3,7935271444726385333e-07 kmol/h
n_{H2O}=2286,0986123926663822 kmol/h
n_{CH4}=8509,9505090853544971 kmol/h
n_{NH3}=35025,47708130517276 kmol/h
n_{AR}=720,76053636279038983 kmol/h
n_{O2}=3,1277028341138844169e-28 kmol/h
n_{N2}=6276,8057891213538824 kmol/h
n_T=225865,29923519739532 kmol/h
y_{CO}=1,5938326759060106568e-11
y_{H2}=0,76614782035532957849
y_{CO2}=1,6795528827659240825e-12
y_{H2O}=0,010121513221081884087
y_{CH4}=0,037677104618995940766
y_{NH3}=0,15507241351329736911
y_{AR}=0,0031911078806853379088
y_{O2}=1,3847646560603158492e-33
y_{N2}=0,027790040392991970791
T: 715.942 °K
p: 180 bar
H: 955600.466527 J/kmol
Gesamtfehler: 0.2342529296875
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -967720,42719452746678 kW
Dampfphase (zum Splitter):
n_{CO}=3,5919800679360487902e-06 kmol/h
n_{H2}=172791,9808745670889 kmol/h
n_{CO2}=3,4311931180523050154e-07 kmol/h
n_{H2O}=40,437602956895986495 kmol/h
n_{CH4}=8434,2136556486948393 kmol/h
n_{NH3}=17636,254775943227287 kmol/h
n_{AR}=715,91067247387968564 kmol/h
n_{O2}=3,1058224377996683993e-28 kmol/h
n_{N2}=6263,9937036229230216 kmol/h
n_T=205882,7912891478336 kmol/h
y_{CO}=1,7446723183159963487e-11
y_{H2}=0,83927354873120507683
y_{CO2}=1,6665759660804406236e-12
y_{H2O}=0,00019641079617261836461
y_{CH4}=0,040966093389900815058
y_{NH3}=0,085661626524661013682
y_{AR}=0,0034772730054982172419
y_{O2}=1,5085391150144488375e-33
y_{N2}=0,030425047495032987027
H2/N2 Verhältnis: 27.5849544316478
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7169114.924407 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,9348748074160143698e-09 kmol/h
n_{H2}=254,2258283836622752 kmol/h
n_{CO2}=3,6233402642033312085e-08 kmol/h
n_{H2O}=2245,6610094357706657 kmol/h
n_{CH4}=75,736853436660240391 kmol/h
n_{NH3}=17389,222305361938197 kmol/h
n_{AR}=4,8498638889107832384 kmol/h
n_{O2}=2,1880396314215860032e-30 kmol/h
n_{N2}=12,812085498430816344 kmol/h
n_T=19982,507946049539896 kmol/h
x_{CO}=3,9709103742032340314e-13
x_{H2}=0,012722418485740936284
x_{CO2}=1,8132560114176170135e-12
x_{H2O}=0,11238133953894259565
x_{CH4}=0,0037901575553538082407
x_{NH3}=0,87022221430831137035
x_{AR}=0,00024270546539625803182
x_{O2}=1,0949774864071487382e-34
x_{N2}=0,00064116503984850336736
T: 294.15 °K
p: 180 bar
H: -67579482.052713 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,873584054348839371e-06 kmol/h
n_{H2}=138233,58469965367112 kmol/h
n_{CO2}=2,74495449444184433e-07 kmol/h
n_{H2O}=32,350082365516790617 kmol/h
n_{CH4}=6747,3709245189565991 kmol/h
n_{NH3}=14109,003820754582193 kmol/h
n_{AR}=572,72853797910374851 kmol/h
n_{O2}=2,4846579502397349885e-28 kmol/h
n_{N2}=5011,1949628983393268 kmol/h
n_T=164706,23303131826106 kmol/h
y_{CO}=1,7446723183830199503e-11
y_{H2}=0,8392735487634466196
y_{CO2}=1,6665759661444639183e-12
y_{H2O}=0,00019641079618016367989
y_{CH4}=0,040966093391474570073
y_{NH3}=0,085661626527951797994
y_{AR}=0,0034772730056318004906
y_{O2}=1,5085391150724010476e-33
y_{N2}=0,030425047496201798602
T: 294.15 °K
p: 180 bar
H: -7169114.924407 J/kmol
========================================
Abgas:
n_{CO}=7,1839601358720963098e-07 kmol/h
n_{H2}=34558,396174913410505 kmol/h
n_{CO2}=6,8623862361046095014e-08 kmol/h
n_{H2O}=8,0875205913791958778 kmol/h
n_{CH4}=1686,842731129738695 kmol/h
n_{NH3}=3527,2509551886446388 kmol/h
n_{AR}=143,18213449477590871 kmol/h
n_{O2}=6,2116448755993352291e-29 kmol/h
n_{N2}=1252,7987407245843769 kmol/h
n_T=41176,558257829557988 kmol/h
y_{CO}=1,7446723183830196271e-11
y_{H2}=0,8392735487634466196
y_{CO2}=1,6665759661444639183e-12
y_{H2O}=0,00019641079618016365278
y_{CH4}=0,040966093391474563135
y_{NH3}=0,085661626527951797994
y_{AR}=0,0034772730056318004906
y_{O2}=1,5085391150724007055e-33
y_{N2}=0,030425047496201791664
T: 294.15 °K
p: 180 bar
H: -7169114.924407 J/kmol
========================================
========================================
==============19. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.917 °K
Vorwärmer (auf T= 573.15 °K), Q: 356365,88080250157509 kW
n_{CO}=3,0634465012083182096e-06 kmol/h
n_{H2}=204705,88536243716953 kmol/h
n_{CO2}=4,0803232189817201575e-07 kmol/h
n_{H2O}=2286,1620608821435781 kmol/h
n_{CH4}=8532,6183706567626359 kmol/h
n_{NH3}=14162,074584638217857 kmol/h
n_{AR}=722,72592014119925352 kmol/h
n_{O2}=0 kmol/h
n_{N2}=16682,343831090292952 kmol/h
n_T=247091,81013331722352 kmol/h
y_{CO}=1,2398009062119258884e-11
y_{H2}=0,82846082697758804958
y_{CO2}=1,6513389160005753285e-12
y_{H2O}=0,0092522777652915954433
y_{CH4}=0,034532178003200623972
y_{NH3}=0,057315030299859535956
y_{AR}=0,0029249286722666197925
y_{O2}=0
y_{N2}=0,067514758267744334752
T: 573.15 °K
p: 180 bar
H: 873022.350285 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -1,4971415201822918988e-07 kW (adiabat)
n_{CO}=3,5613107398672886736e-06 kmol/h
n_{H2}=173370,97316460881848 kmol/h
n_{CO2}=3,7528497193004883571e-07 kmol/h
n_{H2O}=2286,1620604497738896 kmol/h
n_{CH4}=8532,6183701916452264 kmol/h
n_{NH3}=35052,016050765516411 kmol/h
n_{AR}=722,72592014119925352 kmol/h
n_{O2}=-3,1386767211954549946e-18 kmol/h
n_{N2}=6237,373098026646403 kmol/h
n_T=226201,86866812015069 kmol/h
y_{CO}=1,5743949246910902634e-11
y_{H2}=0,76644359388107441422
y_{CO2}=1,6590710507376980053e-12
y_{H2O}=0,010106733750303341715
y_{CH4}=0,037721255003028156261
y_{NH3}=0,15495900302306203633
y_{AR}=0,0031950484069677223542
y_{O2}=-1,3875556111344387664e-23
y_{N2}=0,027574365918161456573
T: 715.733 °K
p: 180 bar
H: 953646.731959 J/kmol
Gesamtfehler: 64.00226894302365
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -968506,59023788652848 kW
Dampfphase (zum Splitter):
n_{CO}=3,5534743039281609232e-06 kmol/h
n_{H2}=173116,7073034660425 kmol/h
n_{CO2}=3,3949354277055314011e-07 kmol/h
n_{H2O}=40,501168459774909536 kmol/h
n_{CH4}=8456,8063979938178818 kmol/h
n_{NH3}=17663,834221735702158 kmol/h
n_{AR}=717,87101162610508709 kmol/h
n_{O2}=-3,1167564721802781268e-18 kmol/h
n_{N2}=6224,6631753571919035 kmol/h
n_T=206220,3832825316058 kmol/h
y_{CO}=1,7231440690909417075e-11
y_{H2}=0,83947427766893112366
y_{CO2}=1,6462656957250849071e-12
y_{H2O}=0,00019639750355185107869
y_{CH4}=0,04100858636305473176
y_{NH3}=0,085655132338913420043
y_{AR}=0,0034810865937271884968
y_{O2}=-1,5113716803583867962e-23
y_{N2}=0,030184519473937292122
H2/N2 Verhältnis: 27.811417650487098
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7171995.655518 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,8364359391287926874e-09 kmol/h
n_{H2}=254,2658611427545452 kmol/h
n_{CO2}=3,5791429159495788247e-08 kmol/h
n_{H2O}=2245,6608919899981629 kmol/h
n_{CH4}=75,811972197828069397 kmol/h
n_{NH3}=17388,181829029806977 kmol/h
n_{AR}=4,8549085150942818956 kmol/h
n_{O2}=-2,1920249015176967146e-20 kmol/h
n_{N2}=12,709922669453932897 kmol/h
n_T=19981,485385588563076 kmol/h
x_{CO}=3,9218485468229874489e-13
x_{H2}=0,012725073053302714612
x_{CO2}=1,7912296550144680623e-12
x_{H2O}=0,11238708482171697045
x_{CH4}=0,0037941109364685418788
x_{NH3}=0,87021467626079773705
x_{AR}=0,00024297035097051831337
x_{O2}=-1,0970280037244483332e-24
x_{N2}=0,00063608497713275597828
T: 294.15 °K
p: 180 bar
H: -67580821.120599 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,8427794431425287386e-06 kmol/h
n_{H2}=138493,36584277285147 kmol/h
n_{CO2}=2,7159483421644251209e-07 kmol/h
n_{H2O}=32,400934767819933313 kmol/h
n_{CH4}=6765,445118395055033 kmol/h
n_{NH3}=14131,067377388560999 kmol/h
n_{AR}=574,29680930088397872 kmol/h
n_{O2}=-2,4934051777442228866e-18 kmol/h
n_{N2}=4979,7305402857537047 kmol/h
n_T=164976,30662602529628 kmol/h
y_{CO}=1,7231440691581559483e-11
y_{H2}=0,8394742777016762636
y_{CO2}=1,6462656957893004567e-12
y_{H2O}=0,00019639750355951191571
y_{CH4}=0,041008586364654341094
y_{NH3}=0,085655132342254539091
y_{AR}=0,0034810865938629744105
y_{O2}=-1,5113716804173404828e-23
y_{N2}=0,030184519475114697518
T: 294.15 °K
p: 180 bar
H: -7171995.655518 J/kmol
========================================
Abgas:
n_{CO}=7,1069486078563197288e-07 kmol/h
n_{H2}=34623,34146069320559 kmol/h
n_{CO2}=6,7898708554110614787e-08 kmol/h
n_{H2O}=8,1002336919549815519 kmol/h
n_{CH4}=1691,3612795987633035 kmol/h
n_{NH3}=3532,7668443471393402 kmol/h
n_{AR}=143,57420232522096626 kmol/h
n_{O2}=-6,2335129443605552906e-19 kmol/h
n_{N2}=1244,9326350714379714 kmol/h
n_T=41244,076656506316795 kmol/h
y_{CO}=1,7231440691581559483e-11
y_{H2}=0,83947427770167615257
y_{CO2}=1,6462656957893004567e-12
y_{H2O}=0,00019639750355951188861
y_{CH4}=0,041008586364654341094
y_{NH3}=0,085655132342254539091
y_{AR}=0,0034810865938629744105
y_{O2}=-1,5113716804173404828e-23
y_{N2}=0,030184519475114690579
T: 294.15 °K
p: 180 bar
H: -7171995.655518 J/kmol
========================================
========================================
==============20. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.798 °K
Vorwärmer (auf T= 573.15 °K), Q: 357011,7524670867715 kW
n_{CO}=3,0326418900020080008e-06 kmol/h
n_{H2}=204965,66650555632077 kmol/h
n_{CO2}=4,0513170667043009484e-07 kmol/h
n_{H2O}=2286,2129132844470405 kmol/h
n_{CH4}=8550,6925645328610699 kmol/h
n_{NH3}=14184,138141272196663 kmol/h
n_{AR}=724,29419146297948373 kmol/h
n_{O2}=-2,4934051777442228866e-18 kmol/h
n_{N2}=16650,879408477707329 kmol/h
n_T=247361,88372802431695 kmol/h
y_{CO}=1,2259940150425170075e-11
y_{H2}=0,82860650726171358738
y_{CO2}=1,6378097569626957928e-12
y_{H2O}=0,0092423815618988009596
y_{CH4}=0,034567543049334119309
y_{NH3}=0,057341648306930469159
y_{AR}=0,00292807517693123966
y_{O2}=-1,0079989447710281897e-23
y_{N2}=0,067313844629293975719
T: 573.15 °K
p: 180 bar
H: 871720.276964 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 2,825631035698784632e-07 kW (adiabat)
n_{CO}=3,5307702739236095846e-06 kmol/h
n_{H2}=173631,57801701896824 kmol/h
n_{CO2}=3,7206481213577418978e-07 kmol/h
n_{H2O}=2286,2129128524525186 kmol/h
n_{CH4}=8550,6925640678000491 kmol/h
n_{NH3}=35073,530467871845758 kmol/h
n_{AR}=724,29419146297948373 kmol/h
n_{O2}=2,7113280379045867826e-18 kmol/h
n_{N2}=6206,1832451778855102 kmol/h
n_T=226472,491402354819 kmol/h
y_{CO}=1,5590283182122917586e-11
y_{H2}=0,76667844709025700922
y_{CO2}=1,64286978004210519e-12
y_{H2O}=0,010094881275407212654
y_{CH4}=0,037755987542330234075
y_{NH3}=0,1548688330785376599
y_{AR}=0,0031981552681212234088
y_{O2}=1,1971997221894805075e-23
y_{N2}=0,0274036957281132941
T: 715.567 °K
p: 180 bar
H: 952126.099111 J/kmol
Gesamtfehler: 40.01293231039046
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -969141,63597618637141 kW
Dampfphase (zum Splitter):
n_{CO}=3,5230115364946980579e-06 kmol/h
n_{H2}=173377,2773230112798 kmol/h
n_{CO2}=3,3662262138673198775e-07 kmol/h
n_{H2O}=40,552072691336356058 kmol/h
n_{CH4}=8474,8207075088557758 kmol/h
n_{NH3}=17686,017708994746499 kmol/h
n_{AR}=719,43525708512083838 kmol/h
n_{O2}=2,6924176773672085446e-18 kmol/h
n_{N2}=6193,5539826197500588 kmol/h
n_T=206491,6570557707455 kmol/h
y_{CO}=1,7061277857846231141e-11
y_{H2}=0,83963332847553662219
y_{CO2}=1,6301996224599216502e-12
y_{H2O}=0,00019638601030153311809
y_{CH4}=0,041041952144755679266
y_{NH3}=0,08565003526277907564
y_{AR}=0,0034840887390545044293
y_{O2}=1,3038869054809880943e-23
y_{N2}=0,029994209309397962954
H2/N2 Verhältnis: 27.993180944178373
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7174257.470650 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,7587374289111113916e-09 kmol/h
n_{H2}=254,30069400768317678 kmol/h
n_{CO2}=3,5442190749042241731e-08 kmol/h
n_{H2O}=2245,6608401611174486 kmol/h
n_{CH4}=75,871856558942340598 kmol/h
n_{NH3}=17387,512758877084707 kmol/h
n_{AR}=4,8589343778586506772 kmol/h
n_{O2}=1,8910360537378608139e-20 kmol/h
n_{N2}=12,629262558134238148 kmol/h
n_T=19980,834346584018931 kmol/h
x_{CO}=3,8830898137161130803e-13
x_{H2}=0,012727230990477764877
x_{CO2}=1,7738093489355806355e-12
x_{H2O}=0,11239074415635448567
x_{CH4}=0,003797231650782989
x_{NH3}=0,87020954502555147858
x_{AR}=0,00024317975393614942969
x_{O2}=9,4642496990260370981e-25
x_{N2}=0,00063206882876973302394
T: 294.15 °K
p: 180 bar
H: -67581703.980588 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,8184092291957589546e-06 kmol/h
n_{H2}=138701,82185840900638 kmol/h
n_{CO2}=2,6929809710938561138e-07 kmol/h
n_{H2O}=32,441658153069084847 kmol/h
n_{CH4}=6779,8565660070853482 kmol/h
n_{NH3}=14148,814167195796472 kmol/h
n_{AR}=575,54820566809678439 kmol/h
n_{O2}=2,1539341418937669898e-18 kmol/h
n_{N2}=4954,8431860957998651 kmol/h
n_T=165193,32564461653237 kmol/h
y_{CO}=1,7061277858519869584e-11
y_{H2}=0,83963332850868810375
y_{CO2}=1,6301996225242874494e-12
y_{H2O}=0,00019638601030928708809
y_{CH4}=0,041041952146376153854
y_{NH3}=0,085650035266160828851
y_{AR}=0,0034840887391920680009
y_{O2}=1,3038869055324700449e-23
y_{N2}=0,029994209310582234385
T: 294.15 °K
p: 180 bar
H: -7174257.470650 J/kmol
========================================
Abgas:
n_{CO}=7,04602307298939421e-07 kmol/h
n_{H2}=34675,455464602244319 kmol/h
n_{CO2}=6,7324524277346376375e-08 kmol/h
n_{H2O}=8,1104145382672694353 kmol/h
n_{CH4}=1694,9641415017708823 kmol/h
n_{NH3}=3537,2035417989482085 kmol/h
n_{AR}=143,88705141702413925 kmol/h
n_{O2}=5,3848353547344155485e-19 kmol/h
n_{N2}=1238,7107965239497389 kmol/h
n_T=41298,331411154125817 kmol/h
y_{CO}=1,7061277858519866352e-11
y_{H2}=0,83963332850868810375
y_{CO2}=1,6301996225242870455e-12
y_{H2O}=0,00019638601030928706098
y_{CH4}=0,041041952146376153854
y_{NH3}=0,085650035266160814973
y_{AR}=0,0034840887391920671336
y_{O2}=1,3038869055324698979e-23
y_{N2}=0,029994209310582230915
T: 294.15 °K
p: 180 bar
H: -7174257.470650 J/kmol
========================================
========================================
==============21. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.702 °K
Vorwärmer (auf T= 573.15 °K), Q: 357530,65626138664084 kW
n_{CO}=3,0082716760552377933e-06 kmol/h
n_{H2}=205174,12252119250479 kmol/h
n_{CO2}=4,0283496956337319413e-07 kmol/h
n_{H2O}=2286,2536366696963341 kmol/h
n_{CH4}=8565,1040121448913851 kmol/h
n_{NH3}=14201,884931079432135 kmol/h
n_{AR}=725,5455878301922894 kmol/h
n_{O2}=2,1539341418937669898e-18 kmol/h
n_{N2}=16625,992054287755309 kmol/h
n_T=247578,90274661555304 kmol/h
y_{CO}=1,2150759384914356863e-11
y_{H2}=0,82872215784548408646
y_{CO2}=1,627097321679522613e-12
y_{H2O}=0,0092344444995362175849
y_{CH4}=0,034595451862515280705
y_{NH3}=0,057363065970182203213
y_{AR}=0,0029305630640618493196
y_{O2}=8,6999906615557194874e-24
y_{N2}=0,067154316744442527076
T: 573.15 °K
p: 180 bar
H: 870705.560286 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -1,1975606282552084194e-07 kW (adiabat)
n_{CO}=3,5065615417277221685e-06 kmol/h
n_{H2}=173840,55341253406368 kmol/h
n_{CO2}=3,6951080068667893801e-07 kmol/h
n_{H2O}=2286,2536362380546962 kmol/h
n_{CH4}=8565,1040116799249517 kmol/h
n_{NH3}=35090,931004426107393 kmol/h
n_{AR}=725,5455878301922894 kmol/h
n_{O2}=-1,7028693931892898718e-18 kmol/h
n_{N2}=6181,4690176144167708 kmol/h
n_T=226689,85667419887614 kmol/h
y_{CO}=1,5468541879963295432e-11
y_{H2}=0,76686516089857337253
y_{CO2}=1,6300279426165233498e-12
y_{H2O}=0,010085381277221782889
y_{CH4}=0,03778335800877842543
y_{NH3}=0,15479709378818468091
y_{AR}=0,0032006089662536350154
y_{O2}=-7,5118905546650558874e-24
y_{N2}=0,027268397043889315567
T: 715.434 °K
p: 180 bar
H: 950939.448254 J/kmol
Gesamtfehler: 0.4310915855835322
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -969653,71292246296071 kW
Dampfphase (zum Splitter):
n_{CO}=3,4988642777572063556e-06 kmol/h
n_{H2}=173586,22288416561787 kmol/h
n_{CO2}=3,3434518177902823404e-07 kmol/h
n_{H2O}=40,59281337986641347 kmol/h
n_{CH4}=8489,1844049473802443 kmol/h
n_{NH3}=17703,840267885367211 kmol/h
n_{AR}=720,68343960060872178 kmol/h
n_{O2}=-1,6910052409411279614e-18 kmol/h
n_{N2}=6168,9035722231019463 kmol/h
n_T=206709,42738603512407 kmol/h
y_{CO}=1,6926486236565131976e-11
y_{H2}=0,8397595846128572683
y_{CO2}=1,6174646023343972778e-12
y_{H2O}=0,00019637620737269551778
y_{CH4}=0,04106820144567387143
y_{NH3}=0,085646022491845719138
y_{AR}=0,003486456562167517155
y_{O2}=-8,1805908044815280681e-24
y_{N2}=0,029843358621748052734
H2/N2 Verhältnis: 28.138910075653843
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7176036.555218 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,6972639705150403429e-09 kmol/h
n_{H2}=254,33052836841554267 kmol/h
n_{CO2}=3,5165618907650730448e-08 kmol/h
n_{H2O}=2245,6608228581858384 kmol/h
n_{CH4}=75,919606732545418026 kmol/h
n_{NH3}=17387,090736540718353 kmol/h
n_{AR}=4,8621482295834397291 kmol/h
n_{O2}=-1,1864152248161480064e-20 kmol/h
n_{N2}=12,565445391314364443 kmol/h
n_T=19980,429288163628371 kmol/h
x_{CO}=3,852401699018308567e-13
x_{H2}=0,012728982185772026031
x_{CO2}=1,7600031718517156395e-12
x_{H2O}=0,11239302176119676802
x_{CH4}=0,0037996984783891956695
x_{NH3}=0,87020606479152684543
x_{AR}=0,00024334553384522646991
x_{O2}=-5,9378865598617269014e-25
x_{N2}=0,00062888765878172422485
T: 294.15 °K
p: 180 bar
H: -67582279.592574 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,7990914222057650845e-06 kmol/h
n_{H2}=138868,9783073324943 kmol/h
n_{CO2}=2,674761454232226084e-07 kmol/h
n_{H2O}=32,474250703893133618 kmol/h
n_{CH4}=6791,3475239579047411 kmol/h
n_{NH3}=14163,072214308294861 kmol/h
n_{AR}=576,54675168048709111 kmol/h
n_{O2}=-1,3528041927529022921e-18 kmol/h
n_{N2}=4935,1228577784813751 kmol/h
n_T=165367,54190882813418 kmol/h
y_{CO}=1,6926486237238650865e-11
y_{H2}=0,83975958464627198374
y_{CO2}=1,6174646023987578264e-12
y_{H2O}=0,00019637620738050952547
y_{CH4}=0,041068201447308015639
y_{NH3}=0,085646022495253645856
y_{AR}=0,0034864565623062464608
y_{O2}=-8,1805908048070400862e-24
y_{N2}=0,029843358622935543811
T: 294.15 °K
p: 180 bar
H: -7176036.555218 J/kmol
========================================
Abgas:
n_{CO}=6,9977285555144116523e-07 kmol/h
n_{H2}=34717,244576833116298 kmol/h
n_{CO2}=6,6869036355805638866e-08 kmol/h
n_{H2O}=8,1185626759732798519 kmol/h
n_{CH4}=1697,8368809894757305 kmol/h
n_{NH3}=3540,7680535770728056 kmol/h
n_{AR}=144,13668792012174436 kmol/h
n_{O2}=-3,3820104818822547673e-19 kmol/h
n_{N2}=1233,7807144446201164 kmol/h
n_T=41341,88547720702627 kmol/h
y_{CO}=1,6926486237238650865e-11
y_{H2}=0,83975958464627187272
y_{CO2}=1,6174646023987576244e-12
y_{H2O}=0,00019637620738050947126
y_{CH4}=0,0410682014473080087
y_{NH3}=0,085646022495253645856
y_{AR}=0,0034864565623062460271
y_{O2}=-8,1805908048070386169e-24
y_{N2}=0,029843358622935543811
T: 294.15 °K
p: 180 bar
H: -7176036.555218 J/kmol
========================================
========================================
==============22. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.625 °K
Vorwärmer (auf T= 573.15 °K), Q: 357947,15296189428773 kW
n_{CO}=2,9889538690652443467e-06 kmol/h
n_{H2}=205341,2789701159636 kmol/h
n_{CO2}=4,0101301787721019115e-07 kmol/h
n_{H2O}=2286,286229220520454 kmol/h
n_{CH4}=8576,5949700957116875 kmol/h
n_{NH3}=14216,142978191930524 kmol/h
n_{AR}=726,54413384258259612 kmol/h
n_{O2}=-1,3528041927529022921e-18 kmol/h
n_{N2}=16606,271725970436819 kmol/h
n_T=247753,11901082715485 kmol/h
y_{CO}=1,2064243150596311695e-11
y_{H2}=0,82881410248216602632
y_{CO2}=1,6185992712353517673e-12
y_{H2O}=0,0092280825296920127726
y_{CH4}=0,034617505540751242199
y_{NH3}=0,057380278540794742159
y_{AR}=0,0029325327436577359325
y_{O2}=-5,4602912696077218944e-24
y_{N2}=0,067027498149255265725
T: 573.15 °K
p: 180 bar
H: 869912.923948 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 2,2158728705512153565e-07 kW (adiabat)
n_{CO}=3,4873403098421748435e-06 kmol/h
n_{H2}=174008,03084065107396 kmol/h
n_{CO2}=3,6748196310300093301e-07 kmol/h
n_{H2O}=2286,2862287891957749 kmol/h
n_{CH4}=8576,5949696308562125 kmol/h
n_{NH3}=35104,97506540921313 kmol/h
n_{AR}=726,54413384258259612 kmol/h
n_{O2}=4,3016425399394744548e-19 kmol/h
n_{N2}=6161,8556823617927876 kmol/h
n_T=226864,28692453957046 kmol/h
y_{CO}=1,5371922822749737751e-11
y_{H2}=0,76701376492338901869
y_{CO2}=1,6198316979932331236e-12
y_{H2O}=0,010077770546360472273
y_{CH4}=0,037804958576329976416
y_{NH3}=0,1547399793123276357
y_{AR}=0,003202549611011486913
y_{O2}=1,8961303245452212983e-24
y_{N2}=0,027160977013589503865
T: 715.328 °K
p: 180 bar
H: 950011.317773 J/kmol
Gesamtfehler: 8.039680946751458
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -970065,99101395125035 kW
Dampfphase (zum Splitter):
n_{CO}=3,4796917787130602244e-06 kmol/h
n_{H2}=173753,67509884663741 kmol/h
n_{CO2}=3,3253577075827484636e-07 kmol/h
n_{H2O}=40,625405850190411172 kmol/h
n_{CH4}=8500,6372946052051702 kmol/h
n_{NH3}=17718,145087608056201 kmol/h
n_{AR}=721,67942014305378962 kmol/h
n_{O2}=4,2716977266795259831e-19 kmol/h
n_{N2}=6149,3408198456954779 kmol/h
n_T=206884,10313071109704 kmol/h
y_{CO}=1,6819522263511213658e-11
y_{H2}=0,83985996247426086825
y_{CO2}=1,6073529368027048094e-12
y_{H2O}=0,00019636794337404505869
y_{CH4}=0,041088885833309315987
y_{NH3}=0,085642854229854445403
y_{AR}=0,0034883270835853233925
y_{O2}=2,064778135132674703e-24
y_{N2}=0,029723602377094860555
H2/N2 Verhältnis: 28.255658645247546
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7177438.053169 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,6485311291143428085e-09 kmol/h
n_{H2}=254,35574180441236081 kmol/h
n_{CO2}=3,4946192344726106507e-08 kmol/h
n_{H2O}=2245,6608229390058113 kmol/h
n_{CH4}=75,957675025653387024 kmol/h
n_{NH3}=17386,829977801160567 kmol/h
n_{AR}=4,8647136995286821559 kmol/h
n_{O2}=2,9944813259948343746e-21 kmol/h
n_{N2}=12,514862516098434142 kmol/h
n_T=19980,183793828451599 kmol/h
x_{CO}=3,8280584459148722779e-13
x_{H2}=0,012730400507555637499
x_{CO2}=1,749042587387428379e-12
x_{H2O}=0,11239440272641253171
x_{CH4}=0,0038016504673320087627
x_{NH3}=0,87020370605348673632
x_{AR}=0,00024347692452413309712
x_{O2}=1,4987256164094670459e-25
x_{N2}=0,00062636373370897802017
T: 294.15 °K
p: 180 bar
H: -67582651.347907 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,783753422970448349e-06 kmol/h
n_{H2}=139002,94007907732157 kmol/h
n_{CO2}=2,6602861660661991944e-07 kmol/h
n_{H2O}=32,50032468015233178 kmol/h
n_{CH4}=6800,5098356841645 kmol/h
n_{NH3}=14174,516070086447144 kmol/h
n_{AR}=577,34353611444294074 kmol/h
n_{O2}=3,4173581813436214606e-19 kmol/h
n_{N2}=4919,4726558765560185 kmol/h
n_T=165507,28250456883688 kmol/h
y_{CO}=1,6819522264185582346e-11
y_{H2}=0,83985996250793459872
y_{CO2}=1,6073529368671505802e-12
y_{H2O}=0,00019636794338191831803
y_{CH4}=0,041088885834956755116
y_{NH3}=0,085642854233288240318
y_{AR}=0,0034883270837251850391
y_{O2}=2,0647781352154607293e-24
y_{N2}=0,029723602378286608644
T: 294.15 °K
p: 180 bar
H: -7177438.053169 J/kmol
========================================
Abgas:
n_{CO}=6,9593835574261187548e-07 kmol/h
n_{H2}=34750,735019769315841 kmol/h
n_{CO2}=6,6507154151654966624e-08 kmol/h
n_{H2O}=8,1250811700380811686 kmol/h
n_{CH4}=1700,1274589210406702 kmol/h
n_{NH3}=3543,6290175216108764 kmol/h
n_{AR}=144,33588402861070676 kmol/h
n_{O2}=8,5433954533590500403e-20 kmol/h
n_{N2}=1229,8681639691385499 kmol/h
n_T=41376,820626142194669 kmol/h
y_{CO}=1,6819522264185582346e-11
y_{H2}=0,83985996250793459872
y_{CO2}=1,6073529368671507821e-12
y_{H2O}=0,00019636794338191831803
y_{CH4}=0,041088885834956755116
y_{NH3}=0,085642854233288254195
y_{AR}=0,0034883270837251854728
y_{O2}=2,0647781352154610967e-24
y_{N2}=0,029723602378286608644
T: 294.15 °K
p: 180 bar
H: -7177438.053169 J/kmol
========================================
========================================
==============23. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.564 °K
Vorwärmer (auf T= 573.15 °K), Q: 358281,18376050889492 kW
n_{CO}=2,9736158698299276112e-06 kmol/h
n_{H2}=205475,24074186081998 kmol/h
n_{CO2}=3,9956548906060750219e-07 kmol/h
n_{H2O}=2286,3123031967793395 kmol/h
n_{CH4}=8585,7572818219705368 kmol/h
n_{NH3}=14227,586833970082807 kmol/h
n_{AR}=727,34091827653844575 kmol/h
n_{O2}=3,4173581813436209791e-19 kmol/h
n_{N2}=16590,621524068508734 kmol/h
n_T=247892,85960656785755 kmol/h
y_{CO}=1,1995568870153701571e-11
y_{H2}=0,82888729053338494612
y_{CO2}=1,6118475122468639726e-12
y_{H2O}=0,0092229857157862405598
y_{CH4}=0,034634951952421999533
y_{NH3}=0,057394097016552896029
y_{AR}=0,0029340938639011437949
y_{O2}=1,3785625720592876405e-24
y_{N2}=0,066926580904345445155
T: 573.15 °K
p: 180 bar
H: 869292.522796 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: 1,5964931911892360597e-07 kW (adiabat)
n_{CO}=3,472058354332368199e-06 kmol/h
n_{H2}=174142,18631617646315 kmol/h
n_{CO2}=3,6586824014094660138e-07 kmol/h
n_{H2O}=2286,3123027657311468 kmol/h
n_{CH4}=8585,7572813572242012 kmol/h
n_{NH3}=35116,28978533334157 kmol/h
n_{AR}=727,34091827653844575 kmol/h
n_{O2}=-4,8349016411663391109e-19 kmol/h
n_{N2}=6146,2700483868811716 kmol/h
n_T=227004,15665613411693 kmol/h
y_{CO}=1,5295131179434049519e-11
y_{H2}=0,7671321480688436667
y_{CO2}=1,6117248491408189436e-12
y_{H2O}=0,010071675939524916618
y_{CH4}=0,037822026732148912587
y_{NH3}=0,15469447917875572829
y_{AR}=0,0032040863435743795369
y_{O2}=-2,1298736165832626901e-24
y_{N2}=0,02707558372024548507
T: 715.243 °K
p: 180 bar
H: 949283.980017 J/kmol
Gesamtfehler: 24.00688074803128
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -970397,47681813372765 kW
Dampfphase (zum Splitter):
n_{CO}=3,4644485192188971934e-06 kmol/h
n_{H2}=173887,8094993524137 kmol/h
n_{CO2}=3,3109639864848355741e-07 kmol/h
n_{H2O}=40,651471682955836684 kmol/h
n_{CH4}=8509,7692677184932109 kmol/h
n_{NH3}=17729,617037066011108 kmol/h
n_{AR}=722,47415719184630234 kmol/h
n_{O2}=-4,8012673913786911887e-19 kmol/h
n_{N2}=6133,7953405792541162 kmol/h
n_T=207024,11677738654544 kmol/h
y_{CO}=1,673451660129297349e-11
y_{H2}=0,83993986883819027334
y_{CO2}=1,599313180459841775e-12
y_{H2O}=0,00019636104389243280548
y_{CH4}=0,041105207450424251225
y_{NH3}=0,085640346218289836733
y_{AR}=0,0034898067356065078093
y_{O2}=-2,3191826468932061754e-24
y_{N2}=0,029628409654936901235
H2/N2 Verhältnis: 28.34913782482528
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7178543.485889 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,6098351134706631032e-09 kmol/h
n_{H2}=254,37681682403675154 kmol/h
n_{CO2}=3,4771841492463110146e-08 kmol/h
n_{H2O}=2245,6608310827746209 kmol/h
n_{CH4}=75,988013638731885635 kmol/h
n_{NH3}=17386,672748267337738 kmol/h
n_{AR}=4,8667610846922357837 kmol/h
n_{O2}=-3,3634249787648636958e-21 kmol/h
n_{N2}=12,474707807626469247 kmol/h
n_T=19980,039878747578769 kmol/h
x_{CO}=3,8087186826612861419e-13
x_{H2}=0,012731547007616403344
x_{CO2}=1,7403289341768694504e-12
x_{H2O}=0,1123952127047438132
x_{CH4}=0,0038031962964853605752
x_{NH3}=0,87020210475285686424
x_{AR}=0,00024358114980052892619
x_{O2}=-1,6833925260318668571e-25
x_{N2}=0,00062435850421439906179
T: 294.15 °K
p: 180 bar
H: -67582889.409388 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,7715588153751179241e-06 kmol/h
n_{H2}=139110,24759948195424 kmol/h
n_{CO2}=2,6487711891878680358e-07 kmol/h
n_{H2O}=32,52117734636467361 kmol/h
n_{CH4}=6807,8154141747954782 kmol/h
n_{NH3}=14183,693629652811069 kmol/h
n_{AR}=577,97932575347704187 kmol/h
n_{O2}=-3,8410139131029528546e-19 kmol/h
n_{N2}=4907,0362724634032929 kmol/h
n_T=165619,29342190924217 kmol/h
y_{CO}=1,6734516601967807467e-11
y_{H2}=0,83993986887206162351
y_{CO2}=1,5993131805243354076e-12
y_{H2O}=0,00019636104390035122183
y_{CH4}=0,041105207452081855835
y_{NH3}=0,085640346221743365862
y_{AR}=0,003489806735747237685
y_{O2}=-2,3191826469867292406e-24
y_{N2}=0,029628409656131692029
T: 294.15 °K
p: 180 bar
H: -7178543.485889 J/kmol
========================================
Abgas:
n_{CO}=6,9288970384377926928e-07 kmol/h
n_{H2}=34777,561899870474008 kmol/h
n_{CO2}=6,6219279729696687659e-08 kmol/h
n_{H2O}=8,1302943365911666262 kmol/h
n_{CH4}=1701,9538535436984148 kmol/h
n_{NH3}=3545,9234074132018577 kmol/h
n_{AR}=144,49483143836923205 kmol/h
n_{O2}=-9,6025347827573797292e-20 kmol/h
n_{N2}=1226,7590681158505959 kmol/h
n_T=41404,823355477303267 kmol/h
y_{CO}=1,6734516601967807467e-11
y_{H2}=0,83993986887206151248
y_{CO2}=1,5993131805243354076e-12
y_{H2O}=0,00019636104390035122183
y_{CH4}=0,041105207452081848896
y_{NH3}=0,085640346221743365862
y_{AR}=0,003489806735747237685
y_{O2}=-2,3191826469867288733e-24
y_{N2}=0,029628409656131692029
T: 294.15 °K
p: 180 bar
H: -7178543.485889 J/kmol
========================================
========================================
==============24. Iteration=============
========================================
========================================
Mischung: Rücklauf + Zulauf + Vorwärmer
========================================
Rücklaufverhältnis = nr/nv = 0.8
Temperatur der Mischung: 402.515 °K
Vorwärmer (auf T= 573.15 °K), Q: 358548,89783455536235 kW
n_{CO}=2,9614212622345971863e-06 kmol/h
n_{H2}=205582,54826226542355 kmol/h
n_{CO2}=3,9841399137277443927e-07 kmol/h
n_{H2O}=2286,3331558629915889 kmol/h
n_{CH4}=8593,0628603126024245 kmol/h
n_{NH3}=14236,764393536446732 kmol/h
n_{AR}=727,97670791557254688 kmol/h
n_{O2}=-3,8410139131029528546e-19 kmol/h
n_{N2}=16578,185140655357827 kmol/h
n_T=248004,87052390826284 kmol/h
y_{CO}=1,1940980255664410069e-11
y_{H2}=0,82894560831798969058
y_{CO2}=1,6064764798010948336e-12
y_{H2O}=0,0092189042539089320616
y_{CH4}=0,034648766543011140506
y_{NH3}=0,057405180646095371744
y_{AR}=0,0029353323036669714749
y_{O2}=-1,5487655161726631399e-24
y_{N2}=0,06684620792178024018
T: 573.15 °K
p: 180 bar
H: 868806.113022 J/kmol
========================================
========================================
Adiabate Ammoniaksynthese: Reaktor
========================================
Berücksichtigte (unabhängige) Reaktionen:
1.9999999999999993 H2O+ 1.0 CH4+ 1.3333333333333333 N2<<==>>1.0 CO2+2.6666666666666665 NH3 K(T)=1.93108e-09
0.9999999999999994 H2O+ 1.0000000000000002 CH4+ 1.0 N2<<==>>1.0 CO+2.0 NH3 K(T)=2.91601e-10
1.9999999999999998 H2O+ 0.6666666666666666 N2<<==>>1.3333333333333333 NH3+1.0 O2 K(T)=1.47386e-41
0.6666666666666666 NH3<<==>>1.0 H2+0.3333333333333333 N2 K(T)=6.03022
Totale zu tauschende Energie, Q: -2,0099004109700519591e-07 kW (adiabat)
n_{CO}=3,4598948395627086811e-06 kmol/h
n_{H2}=174249,60715571115725 kmol/h
n_{CO2}=3,6458335187213294791e-07 kmol/h
n_{H2O}=2286,3331554321794101 kmol/h
n_{CH4}=8593,0628598479597713 kmol/h
n_{NH3}=35125,39179881268501 kmol/h
n_{AR}=727,97670791557254688 kmol/h
n_{O2}=-8,1985200881052273117e-19 kmol/h
n_{N2}=6133,8714380172377787 kmol/h
n_T=227116,24311956128804 kmol/h
y_{CO}=1,5234026382434076327e-11
y_{H2}=0,76722653017811925924
y_{CO2}=1,6052720266256102795e-12
y_{H2O}=0,010066797178520518405
y_{CH4}=0,037835527489437623117
y_{NH3}=0,1546582107750063273
y_{AR}=0,0032053044639891400437
y_{O2}=-3,6098343189787896001e-24
y_{N2}=0,027007629898087786441
T: 715.176 °K
p: 180 bar
H: 948713.066975 J/kmol
Gesamtfehler: 0.7235565187066545
========================================
========================================
Abkühler + Produkt-Abscheider
========================================
Vorkühler (auf T= 294.15 °K), Q: -970663,70300425111782 kW
Dampfphase (zum Splitter):
n_{CO}=3,4523157720605480345e-06 kmol/h
n_{H2}=173995,21287920404575 kmol/h
n_{CO2}=3,2995021562571398376e-07 kmol/h
n_{H2O}=40,672313109402068676 kmol/h
n_{CH4}=8517,0506782320371713 kmol/h
n_{NH3}=17738,810874727168994 kmol/h
n_{AR}=723,10831344447728952 kmol/h
n_{O2}=-8,1415173255166387477e-19 kmol/h
n_{N2}=6121,4286475679373325 kmol/h
n_T=207136,28371006727684 kmol/h
y_{CO}=1,6666880906065422887e-11
y_{H2}=0,84000354624349060639
y_{CO2}=1,5929136590776301017e-12
y_{H2O}=0,00019635532886495149236
y_{CH4}=0,041118101210159949122
y_{NH3}=0,085638356333735357606
y_{AR}=0,0034909785019959518014
y_{O2}=-3,9305124043755706862e-24
y_{N2}=0,029552662322976690906
H2/N2 Verhältnis: 28.423955075966276
Stoechiometrisches Verhältnis: 3
T: 294.15 °K
p: 180 bar
H: -7179416.296270 J/kmol
========================================
Produkt-Flüssigkeit:
n_{CO}=7,5790675021604150189e-09 kmol/h
n_{H2}=254,3942765071357428 kmol/h
n_{CO2}=3,4633136246418997237e-08 kmol/h
n_{H2O}=2245,6608423227780804 kmol/h
n_{CH4}=76,012181615922173705 kmol/h
n_{NH3}=17386,580924085519655 kmol/h
n_{AR}=4,8683944710953195312 kmol/h
n_{O2}=-5,7002762588589256161e-21 kmol/h
n_{N2}=12,442790449300511924 kmol/h
n_T=19979,959409493960266 kmol/h
x_{CO}=3,7933347861270364816e-13
x_{H2}=0,012732472143717730312
x_{CO2}=1,7333937247394858454e-12
x_{H2O}=0,11239566593908976999
x_{CH4}=0,0038044212247864577815
x_{NH3}=0,87020101367808655457
x_{AR}=0,00024366388206108809816
x_{O2}=-2,852996917773854379e-25
x_{N2}=0,00062276355019092539868
T: 294.15 °K
p: 180 bar
H: -67583040.612796 J/kmol
========================================
========================================
Abtrennung: Splitter
========================================
Rücklaufverhältnis = nr/nv = 0.8
Rücklaufstrom:
n_{CO}=2,761852617648438597e-06 kmol/h
n_{H2}=139196,1703033632366 kmol/h
n_{CO2}=2,639601725005711976e-07 kmol/h
n_{H2O}=32,537850487521659204 kmol/h
n_{CH4}=6813,6405425856301008 kmol/h
n_{NH3}=14191,048699781735195 kmol/h
n_{AR}=578,48665075558176341 kmol/h
n_{O2}=-6,5132138604133115759e-19 kmol/h
n_{N2}=4897,1429180543500479 kmol/h
n_T=165709,02696805389132 kmol/h
y_{CO}=1,6666880906740709228e-11
y_{H2}=0,84000354627752471526
y_{CO2}=1,5929136591421699804e-12
y_{H2O}=0,00019635532887290715106
y_{CH4}=0,041118101211825922037
y_{NH3}=0,085638356337205137625
y_{AR}=0,0034909785021373942147
y_{O2}=-3,9305124045348222527e-24
y_{N2}=0,029552662324174062969
T: 294.15 °K
p: 180 bar
H: -7179416.296270 J/kmol
========================================
Abgas:
n_{CO}=6,9046315441210943749e-07 kmol/h
n_{H2}=34799,042575840801874 kmol/h
n_{CO2}=6,5990043125142772929e-08 kmol/h
n_{H2O}=8,1344626218804130247 kmol/h
n_{CH4}=1703,4101356464070705 kmol/h
n_{NH3}=3547,7621749454328892 kmol/h
n_{AR}=144,62166268889541243 kmol/h
n_{O2}=-1,6283034651033274125e-19 kmol/h
n_{N2}=1224,2857295135872846 kmol/h
n_T=41427,256742013451003 kmol/h
y_{CO}=1,6666880906740709228e-11
y_{H2}=0,84000354627752482628
y_{CO2}=1,5929136591421697784e-12
y_{H2O}=0,00019635532887290715106
y_{CH4}=0,041118101211825922037
y_{NH3}=0,085638356337205151503
y_{AR}=0,0034909785021373946484
y_{O2}=-3,9305124045348222527e-24
y_{N2}=0,029552662324174069908
T: 294.15 °K
p: 180 bar
H: -7179416.296270 J/kmol
========================================
Content source: santiago-salas-v/walas
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